REMOVAL REVIEW (Part 2) Flashcards
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In coordination compounds, the splitting of d orbitals leads to the formation of t2g and eg orbitals in an octahedral field.
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Π bonding in coordination compounds involves the overlap of ligand orbitals with the metal ion’s p orbitals.
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The spectrochemical series is used to predict the electronic configuration, magnetic properties, and color of coordination compounds based on the nature of the ligands present.
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In coordination chemistry, Molecular Orbital Theory (MOT) considers the delocalization of electrons over the entire complex and provides a more detailed description of bonding compared to Crystal Field Theory (CFT) and Valence Bond Theory (VBT)
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According to CFT, the strength of the ligand field is determined solely by the metal ion’s identity.
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According to CFT, the strength of the ligand field is determined by multiple factors, including the metal ion’s identity, charge, and the ligands themselves
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VBT suggests that the d orbitals of the metal ion in a coordination compound always participate in hybridization to form metal-ligand bonds.
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VBT suggests that the d orbitals of the metal ion in a coordination compound may or may not participate in hybridization to form metal-ligand bonds, depending on the ligand.
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When naming a coordination compound, the ligands are listed in alphabetical order regardless of their charge.
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In coordination compounds, cationic complexes are named by placing the prefix for the metal before the name of the metal.
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In coordination compounds, cationic complexes are named by placing the prefix for the ligand is placed before the name of the metal
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When naming polydentate ligands in coordination compounds, prefixes like “di-”, “tri-”, and “tetra-” are used without modification.
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When naming polydentate ligands in coordination compounds, prefixes like “di-”, “tri-”, and “tetra-” are used with modifications such as “bis-“, “tris-“, and “tetrakis-“.
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In a coordination compound, the ligands can alter the redox potential of the central metal atom, affecting its catalytic properties.
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The stability of a coordination compound under reaction conditions is crucial for its effectiveness as a catalyst.
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Only transition metals can form coordination compounds that act as catalysts.
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