Relative mass - 2.2 - (2) Flashcards

Page 13 & 14

1
Q

What do most elements contain a mixture of?

A

isotopes, each with a different relative isotopic mass

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2
Q

What is relative atomic mass?

A

the weighted mean mass of an atom of an element relative to 1/12th of the mass of an atom of carbon-12

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3
Q

What does the weighted mean mass take account of?

A

the percentage abundance of each isotope and the relative isotopic mass of each isotope

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4
Q

In the periodic table, in addition to the atomic number, each element is…

A

shown with its relative atomic mass

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5
Q

How are percentage abundances of the isotopes in a sample of an element found?

A

using a mass spectrometer

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6
Q

Are there different types of mass spectrometers?

A

yes

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7
Q

Do all mass spectrometers work to the same basic principle?

A

yes

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8
Q

Basic principle of mass spectrometers - 1) A sample is…

A

placed in the mass spectrometer

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9
Q

Basic principle of mass spectrometers - 2)The sample is vaporised and then…

A

ionised to form positive ions

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10
Q

Basic principle of mass spectrometers - 3) The ions are accelerated. Heaver ions move more…

A

slowly and are more difficult to deflect than lighter ions, so the ions of each isotope are separated

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11
Q

Basic principle of mass spectrometers - 4) The ions are detected on a mass…

A

spectrum as a mass-to-charge ratio m/z.

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12
Q

Basic principle of mass spectrometers - 4.1) Each ion reaching the detector adds to the…

A

signal so the greater the abundance, the larger the signal

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13
Q

mass-to-charge ratio m/z =

A

relative mass of ion / relative charge on ion

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14
Q

For an ion with one positive charge, what is this ratio equivalent to?

A

the relative isotopic mass, which is recorded on the x-axis of the spectrum

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15
Q

What is the percentage abundance?

A

how much of that isotope we have

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16
Q

What does m/z / mass to charge ratio mean?

A

tells us the different isotopes that have come through the mass spectra

17
Q

To calculate relative atomic mass - 1) Multiply them all, add them together and then…

A

divide them by 100 or total abundance

18
Q

To calculate relative atomic mass - Add up all abundances for…

A

total abundance

19
Q

To calculate relative atomic mass - After you get the answer after dividing by total abundance or 100, look at the…

A

periodic table to see which element it is