redox titrations Flashcards

1
Q

what is an alkali

A

a base that releases hydroxide ions in aqueous solution

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

what 2 approximations are made when calculating PH of a weak acid

A

that the H+ conc is equal to A- conc
the HA at equilibrium is equal to the initial conc.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

what is the initial colour change when thiosulfate-iodine titration is carried out?

A

Orange fades to yellow as iodine is used up.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

what colour change do you look for when adding manganate solution.

A

colourless changes to permanent pink

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

what does a big pKa mean

A

the acid is weak

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

what does a big Ka mean

A

the acid is strong as the acid dissociation lies closer to the right

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

what is a salt bridge

A

concentrated solution of an electrolyte soaked into filter paper to connect two half-cells

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

what does an oxidising agent do

A

takes electrons from the species that is oxidised

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

when does the approximation H+= A- for a weak acid breakdown

A

very dilute solutions or weak acids the H+ from the water dissociation is significant compared with the H+ from the acid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

when should you add the iodine in an iodine-thiosulfate titration

A

only when faded to pale yellow

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

what colour is phenolphthalein in acid and in alkali

A

colourless in acid
pink in alkali

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

what does a fuel cell do

A

uses energy from the reaction of a fuel with oxygen to create a voltage

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

define a base

A

a substance that reacts with an acid to make a salt

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

what does a reducing agent do

A

it donates a pair of electrons to the species that is being reduced

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

what is the difference when reading the burette scale with a manganate titration

A

read from the top of the meniscus because its dark purple you cant see the bottom of the meniscus

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

when does the approximation that HA at equm =initial HA not work

A

when the weak acid is still quite strong as quite a lot of the HA will dissociate so this isn’t true

17
Q

give 2 limitations of predictions of feasibility using electrode potentials

A

reactions may have too high an activation energy so the reaction may not take place.
the reaction may not take place with 1moldm-3

18
Q

what is the name of the species made when H+ dissolves in water

A

hydronium ion, H3O+

19
Q

Kw chnages with temperature. will the PH of water be 7 at all temperatures

A

NO

20
Q

What is the Kw expression

A

Kw= [H+][OH-]

21
Q

if a standard electrode potential is very negative, what does this tell us for the likelihood og gaining/losing electrons

A

likely to lose electrons/ be oxidised

22
Q

write the Ka expression for a weak acid

A

Ka= [H+][A-]
[HA]

23
Q

what indicator is used at the end of a iodine-thiosulfate titration

A

starch solution

24
Q

what is the name of Kw

A

ionic product of water