Redox Reactions Flashcards
Reduction reaction
Conditions
Equations
LiAlH4 used in dry ether
RCHO + [H] —> ROH
RCOR + [H] —> ROHR
Ketones cannot be oxidised but aldehydes can
List the reagents that can oxidise aldehydes to carboxylic acids
Acidified potassium dichromate
Fehling’s solution
Benedict’s solution
Tollen’s reagent
Oxidation reaction equation of aldehydes
RCHO + [O] —> RCOOH
Acidified potassium dichromate
Colour change
Why
Orange solution —> green solution
Colour change is due to chromium +6 changing to +3
Fehling’s solution
Colour change
Deep blue solution —> red ppt
Benedict’s solution
Colour change
Why for Benedicts and Fehling’s
Deep blue solution —> red ppt
Conversion of copper (II) complex to copper (I) oxide
Tollen’s reagent
Colour change
Why
Colourless solution —> silver mirror
Conversion of silver (I) complex to metallic silver