Bonding And Physical Properties Flashcards
C=O bonding description
Polarity and location of greatest electron density
Made of a sigma and pi bond
Polar due to oxygen and oxygen has greatest electron density
Physical properties of aldehydes
Distinctive smell
Small chains have unpleasant smells
Long chains have pleasant smells
Physical properties of ketones
Lower ketones smell of solvents
Boiling temperatures of aldehydes and ketones and why / bonding that can be formed
Have LDF and permanent dipole-dipole attractions but no hydrogen bonding
Boiling temp increases with molar mass as LDF increase
Most liquid at room temp
Solubility of aldehydes and ketones
Smaller are soluble in water as they can form hydrogen bonds
Solubility decreases as hydrocarbon part of the molecule interrupts hydrogen bonds