Bonding And Physical Properties Flashcards

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1
Q

C=O bonding description
Polarity and location of greatest electron density

A

Made of a sigma and pi bond
Polar due to oxygen and oxygen has greatest electron density

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2
Q

Physical properties of aldehydes

A

Distinctive smell
Small chains have unpleasant smells
Long chains have pleasant smells

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3
Q

Physical properties of ketones

A

Lower ketones smell of solvents

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4
Q

Boiling temperatures of aldehydes and ketones and why / bonding that can be formed

A

Have LDF and permanent dipole-dipole attractions but no hydrogen bonding
Boiling temp increases with molar mass as LDF increase
Most liquid at room temp

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5
Q

Solubility of aldehydes and ketones

A

Smaller are soluble in water as they can form hydrogen bonds
Solubility decreases as hydrocarbon part of the molecule interrupts hydrogen bonds

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