Redox Flashcards
Oxidation numbers are like
Like the charge of an atom in a molecule/compound which is quoted per atom
Rules for reassigning oxidation numbers and “hierarchy”:
Elemental=0 Group 1-3 = positive group number F=-1 Hydrogen=+1 Oxygen=-2 Then group seven=-1 Group six =-2 Group 5=-3 Then everyone else
Roman numerals refer to what is in front of the number but not “ates” or “ites”
Sodium chlorite (VII) - what has the oxidation number of 7?
Iron (III) chloride
Chlorine
Iron
OILRIG and relate to oxidation numbers
Oxidation is loss Reduction is gain
Oxidation = number becomes more positive
Reduction = number becomes more negative
What is disproportionation?
When an element in a singly species is both oxidised and reduced in a single reaction.
Oxidising agent
Causes another substance to be oxidised - it itself is reduced
Reducing agent def
Causes another substance to be reduced - it itself is oxidised
Generally metals are —— agents
Reducing because they like to lose electrons
Generally non - metals are —— agents
Oxidising agents because they like to gain electrons
How do you combine ionic half equations?
By multiplying to make the number of electrons the same then adding whatever is in the right to the right of the final equation and whatever is on the left to the left of the final equation
Make an ionic equation under acidic conditions
Balance oxidation number with electrons
Balance excess oxygen with H2O on the other side
Balance with H+ on non-H2O side
Check the charges balance
Form an ionic equation under alkaline conditions
Balance oxidation number with electrons
Match excess oxygen with H2O on the same side
Balance with OH- on opposite side to H2O
Check the charges balance