Redox Flashcards

1
Q

What is standard electrode potential

A

The EMF of a cell with the given electrode and the standard hydrogen electrode

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2
Q

What substance is used in the salt Bruges

A

Potassium nitrate

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3
Q

What are electrodes made of in emf

A

Platinum

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4
Q

What is the purpose of an acid/alkali in a fuel cell

A

Increase the surface area

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5
Q

Advantages of hydrogen oxygen fuel cells

A

Only waste water
Less pollution
Greater efficiency than fossil fuel
No recharging

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6
Q

Disadvantages of hydrogen oxygen fuel cells

A

Need constant fuel supply
Expensive
Hard to safely store hydrogen
Limited lifetime
Use of toxic chemicals in production

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7
Q

Half equation for hydrogen in acid fuel cell

A

H2 becomes 2H+ and 2e-

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8
Q

Half equation for oxygen in acid fuel cell

A

O2 + 4H+ + 4e- becomes 2H2O

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9
Q

What is the half equation for hydrogen in an alkali fuel cell

A

H2 + 2OH- becomes 2H2O + 2e-

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10
Q

What is the half equation for oxygen in an alkali fuel cell

A

O2 + 2H2O + 4e- becomes 4OH-

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11
Q

What are the E cell values for fuel cells

A

+1.23V

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12
Q

How does the E cell change between alkali and acid hydrogen fuel cells and why

A

Does not change as redox reaction is the same

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13
Q

How to calculate e cell value

A

Take more negative half equation
Reverse it

E cell = E(reduced) - E(oxidised)

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14
Q

Ratio of Fe 2+ to MnO4- in titration

A

5:1

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15
Q

Ratio of C2O4 2- to MnO4- in titration

A

5:2

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16
Q

Why is the titration between MnO4- and C2O42- slow originally and how does this change

A

Both negative ions so repel one another
Initially heated

Speeds up as Mn2+ formed- autocatalyst

17
Q

How is the conc of oxidising agents found

A

Sodium thiosulphate used

Ox agent added to iodine and titrated

18
Q

Ratio of thiosulphate to iodine in titration

A

2:1