Redox 1 Flashcards

1
Q

what is oxidation

A

“oxidation” is defined as the addition
of oxygen/electronegative element to
a substance or removal of hydrogen/
electropositive element from a substance.

It also involves the loss of electrons

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2
Q

what is reduction

A

removal
of oxygen/electronegative element from
a substance or addition of hydrogen/
electropositive element to a substance.

also involves the gain of e-s

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3
Q

what is reaction between potassium ferocyanide and hydrogen perxode considered to be

A

2K4 Fe(CN)6 + H2O2 (aq) →2K3Fe(CN)6
+ 2 KOH (aq

The e removal
of electropositive element potassium from
potassium ferrocyanide before it changes to
potassium ferricyanide

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4
Q

what is oxidising agent

A

a substance that supplies oxygen or other electro-ve elemtn or remove hydrogen or any other electro+ve element.
it gets reduced

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5
Q

what is reducing agent

A

a substance that supplies hydrogen or other electro+ve element or remove oxygen or any other electro-ve element.

it gets oxidised

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6
Q

zn rod in cuso4 solution

A

You may notice
that the strip becomes coated with reddish
metallic copper and the blue colour of the
solution disappears. Formation of Zn2+ ions
among the products can easily be judged
when the blue colour of the solution due to
Cu2+ has disappeared. If hydrogen sulphide
gas is passed through the colourless solution
containing Zn2+ ions, appearance of white zinc
sulphide, ZnS can be seen on making the
solution alkaline with ammonia.
The reaction between metallic zinc and the
aqueous solution of copper nitrate is :
Zn(s) + Cu2+ (aq) → Zn2+ (aq) + Cu(s)

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7
Q

co in nickel solution

A

the reaction of metallic cobalt placed in nickel
sulphate solution. At equilibrium, chemical tests reveal that both
Ni2+(aq) and Co2+(aq) are present at moderate
concentrations. In this case, neither the
reactants [Co(s) and Ni2+(aq)] nor the products
[Co2+(aq) and Ni (s)] are greatly favoured.

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8
Q

what is competitive elctron transfer

A

There is a competition for the release of electrons by different metals. The different metals are ranked according to their e- losing capability in the metal reactivity series.

electrochemical series

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9
Q

what is oxidation number

A

Oxidation number denotes the oxidation
state of an element in a compound
ascertained according to a set of rules
formulated on the basis that electron pair in a covalent bond belongs entirely to more
electronegative element.

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10
Q

differentiate between valency and oxidation state

A

Valency
- it is combining capacity of the atom
- valency of an element is just a no without any sign
- except noble gases, no other element has 0 valency
- valency is always a whole no
- in most cpds, an element has a fixed no for valency

oxidn state
- it is the charge assigned to the element based on some fixed rules
- it has +ve or -ve sign
- all elements have 0 oxidn state in free/ uncombined state
- oxidation can even be a fraction
- the oxidn state of an element is different in different cpds. Oxygen

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11
Q

what is stock notation

A

the oxidation
number is expressed by putting a Roman
numeral representing the oxidation number
in parenthesis after the symbol of the metal in
the molecular formula
AuCl SIlver (I) Chloride
AuCl3 Silver (III) Chloride

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12
Q

what are redox reactions

A

Oxidation: An increase in the oxidation
number of the element in the given substance.
Reduction : A decrease in the oxidation
number of the element in the given substance.
Oxidising agent: A reagent which can
increase the oxidation number of an element
in a given substance. These reagents are
called as oxidants also.
Reducing agent: A reagent which lowers the
oxidation number of an element in a given
substance. These reagents are also called as
reductants.
Redox reactions: Reactions which involve
change in oxidation number of the interacting
species

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13
Q
A
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