Reagents used Flashcards
1
Q
Clemmensen Reduction.
A
for aldehydes and ketones. Zg(Hg) and HCl
2
Q
Wolff-Kischner Reduction
A
for aldehydes and ketones. NH2NH2, heat, KOH
3
Q
Forming Diazonium Salt.
A
NO2 with 1. Sn/HCl 2. H2O,Base
NH2 ‘anilines’ with NaNO2 with aq. Acid
4
Q
Oxidation of Alkylbenzene (Alkyl Halide on a benzene to carboxylic acid)
A
Na2Cr2O7, H2SO4, heat, water
5
Q
1,2-diol synthesis from Alkene (2 options)
A
- OsO4
- peroxide, OH-
or - KMnO4, OH-, cold
- H2O
6
Q
Cyclopropane Synthesis
A
CH2I2, Zn/Cu
7
Q
Vicinal Dihalide -> Epoxide
A
NaOH/KOH (base) in water
8
Q
Fischer Esterification
A
converts carboxylic acid to an ester in Ethanol solvent with acid. “acid catalyzed esterification”
9
Q
Claisen (Ester) Condensation
A
typically NaOEt as base, then Acid.
- NaOCH2CH3
- H30+