Reagents Flashcards
What are the essential conditions for free radical substitution
UV light
What are the essential conditions for nucleophilic substitution of haloalkanes
Warm aqueous NaOH (or KOH)
What conditions are needed for addition Polymerisation of alkenes
High temp
High pressure
Initiator/catalyst
What 2 conditions are needed for a hydrogenation reaction of alkene - breaks double bond (electrophilic addition)
150*c
Nickel catalyst
What happens in hydration of alkenes
H2O is added across double bond
Alkene -> alcohol
What happens in electrophilic addition
Alkene -> alkane Hydrogen added (H2, HBr)
4 conditions needed for hydration of alkenes
High pressure (60-70atm)
300*c
H3PO4 catalyst (phosphoric acid catalyst)
Steam
What’s test for alkenes
Bromine water goes from orange -> colourless if positive
What is used in simple oxidation reactions of alcohols as an oxidant agent
Acidified potassium dichromate (VI) K2CrO7
Or
H2SO4
If the K2Cr7O7 oxidises something what would the colour change be
Orange -> green
Oxidation must have occurred
What does a 1y alcohol oxidise to
Aldehyde -> Carboxylic acid
-CHO -COOH
What does a 2y alcohol oxidise to
Ketone C=O
What conditions are used for elimination of alcohols back to alkenes (dehydration)
Hot concentrated sulphuric/phosphoric acids