Reactivity Series And Redoz Flashcards

1
Q

What are easiest metals to extract

A

The least reactive metals like gold beacsue they can be found as native metals and occur naturally as their metal

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2
Q

How do you extract moderately reactive metals

A

Metals below carbon can be extracted cheaply and easily by heating their ores with carbon to bring about a displacement reaction. These metals are not found native because they combine with oxygen or moisture in the air to from compounds

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3
Q

How do you extract metals more reactive than carbon

A

By electrolysis

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4
Q

What are the three raw materials fed into the top of the blast furnace

A

Iron ore , coke , limestone and blast of hot air

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5
Q

What does the coke do

A

Burnis in hot air to form carbon dioxidE. This reaction is very exothermic and provides the high temperatures needed for the furnace to function . Higher up in the furnace carbon dioxide reacts with more coke to form carbon monoxide

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6
Q

What does the carbon monoxide do

A

Reacts with iron oxide ( haematite) to form carbon dioxide and molten iron which collects at the base of the furnace where it can be tapped off .

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7
Q

What does the calcium carbonate do

A

Thermally decomposes to form calcium oxide and carbon dioxide . Calcium oxide reacts with silicon dioxide impurities to make calcium silicate which forms slag that floats on top of the molten iron and can be tapped off seperately and used for road surfacing and cement making

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8
Q

How is steel made

A

Most of carbon is removed from the pig iron making it stronger than cast iron and it’s used for construction . This is done by basic oxygen process , oxygen gas is bubbled through molten pig iron making most of the carbon present burn off as carbon dioxide gas leaving mild steel . Calcium oxide is also added to take away impurities . Other metals can be addressed to make stainless steel which is very resistant to corrosion so is therefore used for cutlery

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9
Q

Cast iron

A

Iron from the blast furnace impure , very hard but brittle used for guttering . Wrought iron is pure iron and used for decoration

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10
Q

High carbon steel

A

Makes steel harder but more brittle so used for cutting tools

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11
Q

Reduction

A

Gain of electrons loss of oxygen

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12
Q

Oxidation

A

Gain of oxygen loss of electrons

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13
Q

Why aluminium dissolved in cryolite

A

Needs to be molten to conduct electricity , cryolite has a lower melting point than aluminium making electrolysis cheaper and easier

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14
Q

What is the cathode for electrolysis of aluminium

A

Graphite lining of electrolysis cell . Molten aluminium sinks to bottom of cell on cathode and can be talked off

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15
Q

What are the anodes for electrolysis of aluminium

A

Graphite anodes dipped into electrolyte . Oxygen glass forms here and is hot so it causes the electrodes to burn away making it expensive as they have to be replaced

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16
Q

How do you extract zinc

A

Roast zinc sulphide in air to give zinc oxide
- React it with sulphuric oxide to give zinc sulphate then electrolyse using l ad anode and aluminium cathode
Or - thermal extraction mic zinc oxide with coke and displace lent reaction will occur forming carbon monoxide zinc
Carbon monoxide removes oxygen from zinc oxide to give zinc and carbon dioxide

17
Q

What is nickel

A

Corrosion resistant

18
Q

What is rusting

A

Redox reaction , iron atoms in the metal loose electrons to form iron 3 ions in the rust iron oxide. The oxygen with it reacts is reduced and gains these electrons

19
Q

How do you prevent rusting

A
  1. Barriers e.g. Painting
    2.alloying this iron
  2. Use sacrificial metals , galvanised iron is iron coated with a layer of zinc which is more reactive than iron so it corrodes instead of the iron
    Zinc looses electrons to from zinc ions
20
Q

Reactivity series

A

Postassium sodium lithium calcium magnésium aluminium carbon zinc iron hydrogen copper

21
Q

What colour does iron turn when oxidised

A

Colourless to yellow

22
Q

Colour change iodide

A

Colourless to brown

23
Q

Colour change bromine

A

Colourless to orange

24
Q

Rust chemichal name

A

Hydrated iron oxide

25
Q

What happens when sulphur is heated

A

Melts then ignites biting with a blue flame forming sulphur dioxide

26
Q

What is air mainly

A

Nitrogen and oxygen (1/5)

27
Q

How do show how much I uber is in air

A

Push 100cm3 of air backwards and forwards over heated cooled which will go black as copper oxide is formed .eventualky all oxygen in air will be used and reaction will stop leaving 79cm3 in the gas syringe

28
Q

How is oxygen made in the lab

A

Hydrogen peroxide solution using manganèse oxide as the catalyst

29
Q

How do you make carbon dioxide

A

Dilute hydrochloride acid and and calcium carbonate in marble chips

30
Q

What happens with magnesium and steam

A

Magnésium burns with a bright white flame producing hydrogen that is ignited at the end of the delivery tube . Metals below hydrogen don’t react with stems

31
Q

How do you take pure salt from rock salt

A

Crush rock salt and mix it with hot water , the salt will dissolve and the impurities won’t do the impurities can be filtered off

32
Q

How do you make pure water from sea water

A

Water boils and is condensed into liquid by a condenser whereas salt from sea water remains in te flask

33
Q

What is recrystallisation used for

A

Purify substances contaminated with small quantities of other soluble substances , dissolve impure solid in hot water ,and then allow to cool impurities will stay in solution and crystals can be filtered

34
Q

What is paper chromatography

A

Spot of ink put on chromatography paper and hung in a boiling tube containing some solvent , solvent soaks up into the paper and the sealed tube stops it from evaporating . Dyes that make up the ink will differ in how strongly they stick to the paper and how soluble they are in the solvent .