Reactivity 1.1 And 1.2 Additional Flashcards
What are the three types is systems?
Open - exchanges energy and matter with the surroundings
Closed - only nerdy is exchanged with the surroundings
Isolated - nothing can be exchanged
Assumptions for experiments
Rate of heat loss is constant
Density of all solutions is the same as water
Ignore the specific heat capacity of the container
What are the limitations of bond energies?
It’s an average of bonds in different molecules
All substance need to be in gaseous form
How does bond enthalpy affect bond length or polarity?
Bond length - shorter bonds tend to be stronger (higher enthalpy)
Polarity - electron distribution in a bond, influencing overall bond strength depending on electronegativity difference
Hess’s law
States that the enthalpy change for a chemical reaction is independent of the route taken
Standard enthalpy of formation
Enthalpy change when 1.00 mol of a substance is formed from its elements in their standard states, under standard conditions
Lattice enthalpy definition
Is when 1.00 mil of an ionic compound is decomposed into its ions in gaseous state under standard conditions
Electron affinity definition
Enthalpy change when 1.00 mol of gaseous atoms gains 1.00 mol of electrons to form 1.00 mol of gaseous ions with a 1- charge, under standard conditions
Enthalpy of atomisation definition
Is the enthalpy change when 1.00 mol of gaseous atoms are formed, under standard conditions
What is complete combustion?
When fuels are burnt in excess oxygen
Biofuels definition
Are derived from biomass that was once alive. There is a net 0 CO2 output unlike fossil fuels
Fuel cells definition
A method to create a current from the reaction hydrogen and water or methanol and water. Climate friendly
As fuel enters the cell is becomes oxidised which sets up a potential difference or voltage within the cell
Fossil fuels definition and what are the 3 main types?
Fossil fuels are the remains of creatures and plants that lived millions of years ago
3 main types are coal, natural gas and crude oil