Reactions of metals Flashcards
Recite the reactivity series from most to least reactive metal.
Include carbon and hydrogen for reference.
- Potassium
- Sodium
- Lithium
- Calcium
- Magnesium
- Carbon
- Zinc
- Iron
- Hydrogen
- Copper
- Gold
State the general word equation for the reaction of a metal with water.
metal + water → metal hydroxide + hydrogen
sodium + water →
sodium hydroxide + hydrogen
State the general word equation for the reaction between a metal and an acid.
metal + acid → salt + hydrogen
Which salt is made when magnesium reacts with hydrochloric acid?
magnesium chloride
copper + sulfuric acid →
copper sulfate + hydrogen
State the general word equation for the reaction between a metal and oxygen.
metal + oxygen → metal oxide
magnesium + oxygen →
magnesium oxide
2Mg + O2 → 2MgO
Why is this reaction described as oxidation?
Because magnesium gains oxygen
2CuO(s) + C(s) → 2Cu(l) + CO2(g)
In this reaction, which element is oxidised?
Carbon
2CuO(s) + C(s) → 2Cu(l) + CO2(g)
In this reaction, which element is reduced?
Copper
What is reduction?
The loss of oxygen in a chemical reaction
Describe what happens in a displacement reaction.
A more reactive metal displaces a less reactive metal from its compound
Magnesium + copper sulfate → magnesium sulfate + copper
What kind of chemical reaction is this?
Displacement
iron + copper sulfate →
iron sulfate + copper
Why is there no reaction when copper is added to magnesium sulfate?
Because copper is less reactive than magnesium (so copper cannot displace magnesium)
Mg(s) + CuSO4(aq) → MgSO4(aq) + Cu(s)
What is the half equation for the oxidation of magnesium?
Mg(s) → Mg2+(aq) + 2e-
Mg(s) + CuSO4(aq) → MgSO4(aq) + Cu(s)
What is the half equation for the reduction of copper?
Cu2+(aq) + 2e- → Cu(s)
What is oxidation in terms of electrons?
Oxidation is the loss of electrons
What is reduction in terms of electrons?
Reduction is the gain of electrons
What is a redox reaction?
When reduction and oxidation take place at the same time.
What does OIL RIG stand for?
Oxidation
Is
Loss (of electrons)
Reduction
Is
Gain (of electrons)
What is an ore?
A rock containing enough quantities of a mineral for extraction to be possible
What is a disadvantage of using electrolysis to extract a metal?
Large amounts of electrical energy are needed, so electrolysis is expensive
Which metals can be extracted using carbon?
- Zinc
- Iron
- Copper
Describe how copper is extracted from its ore using carbon.
Copper oxide is heated with carbon to form copper and carbon dioxide.
Copper oxide + carbon → copper + carbon dioxide
Which element is oxidised and which element is reduced when copper is extracted using carbon?
- Carbon is oxidised
- Copper is reduced
Iron(III) oxide is reduced to molten iron when it reacts with carbon.
What is the word equation for this reaction?
iron(III) oxide + carbon → iron + carbon monoxide
Why must aluminium be extracted from its compound using electrolysis, not heating with carbon?
Because aluminium is more reactive than carbon (so carbon cannot displace aluminium from its compounds)
Why is aluminium more expensive than iron?
Because of the large amounts of electrical energy used in the extraction process (electrolysis).
What are two ways that aluminium oxide can be made into an electrolyte?
- It is melted (very expensive)
- Powdered aluminium oxide is dissolved in molten cryolite (less expensive)
Why is the electrolysis of aluminium oxide so expensive?
- Aluminium oxide has a very high melting point
- A lot of energy is required to break its ionic bonds
What is formed at the cathode during the electrolysis of aluminium oxide? How does this product form?
At the cathode, aluminium ions gain electrons and form aluminium atoms
What is formed at the anode in the electrolysis of aluminium oxide? How is this product formed?
At the anode, oxide ions lose electrons and form oxygen gas
Oxygen is produced at the anode in the electrolysis of aluminium chloride.
What is the half equation for the reaction at the anode?
2O2- → O2 + 4e-
Aluminium is produced at the cathode in the electrolysis of aluminium oxide.
What is the half equation for this reaction?
Al3+ + 3e- → Al