reactions of alkenes Flashcards

1
Q

are alkenes more reactive than alkanes and why

A

yes because they have double bonds

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2
Q

in ALKANES what are the single bonds between two carbon atoms called

A

sigma bonds

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3
Q

a double bond is…

A

stronger than a single bond

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4
Q

in an alkene the double bond is made up of..

A

a sigma bond and a pi bond.

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5
Q

when an alkene reacts which bond remains intact and which breaks

A

the sigma bond remains intact whilst the pi bond breaks.

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6
Q

what reactions to alkenes take part in

A

addition reactions

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7
Q

what’s an addition reaction

A

a small molecule is added across the double bond , causing the pi bond to break

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8
Q

an unsaturated alkene forms a…

A

saturated molecule

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9
Q

what’s the addition of hydrogen

A

a mixture of hydrogen gas and gaseous alkene is passed over a catalyst of nickel at a temp of 150 degrees Celsius.

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10
Q

what happens in the addition of hydrogen

A

hydrogen adds across the double bond and an alkane is formed.

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11
Q

what’s the reaction name for the addition of hydrogen

A

hydrogenation

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12
Q

what’s the addition of halogens

A

alkenes react rapidly with halogen such as chlorine and bromine at room temperature

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13
Q

what happens in the addition of halogens

A

the halogen adds across the double bond to give a halogenoalkane.

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14
Q

what’s the reaction name of addition of halogens

A

halogenation , more specifically bromination , chlorination if Br and Cl used.

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15
Q

what happens when bromine is added to a sample containing an alekene

A

changes from orange to colourless.

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16
Q

what does the colour change show(bromine added to sample w alkene and goes from orange to colourless)

A

shows bromine has been added across the double bond

additional info- the reaction was used for a test of saturation and to prove the presence of a double bond.

17
Q

what’s addition of hydrogen halides

A

a hydrogen halide such as HCl , HBr and Hl add across the double bond to form a halogenoalkane.

18
Q

what’s addition of steam

A

steam and the gaseous alkene are to a high temperature and pressure in the presence of phosphoric acid catalyst.

19
Q

when is the addition of steam to alkenes used

A

as a method to prepare alcohols.

20
Q

what’s addition to unsymmetrical alkenes.

A

unsymmetrical alkenes also take part on addition reactions , forming a mixture of organic products.

21
Q

what’s markownikovs rule

A

when an asymmetrical alkene reacts with a hydrogen halide the hydrogen adds to the carbon atom that is already bonded to the greatest number of hydrogens