Reactions Flashcards

1
Q

HYDRATION
-Write the simple equation for this

A

alkene + water = alcohol

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2
Q

HYDRATION
-How do you do these reactions?

A
  1. Break double bond
  2. OH goes to carbon & H goes to the other
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3
Q

DEHYDRATION
-Write the simple equation for this

A

alcohol - water = alkene

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4
Q

DEHYDRATION
-In this case you are removing water from (the same/different) molecule

A

The same

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5
Q

DEHYDRATION
-What happens to the bonds

A

The single bond becomes a double bond

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6
Q

DEHYDRATION
-How do you do these types of reactions?

A
  1. One carbon loses H and the other loses OH
  2. Double bond between the two carbons
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7
Q

DEHYDROGENATION
-Describe how the bonds change

A

You go from an alkane to an alkene

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8
Q

DEHYDROGENATION
-What happens here?

A

You lose 2 hydrogen atoms so it becomes an alkene

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9
Q

OXIDATION
-What is this?

A

Losing hydrogens or gaining oxygens

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10
Q

OXIDATION
-Can tertiary alcohols be oxidized?

A

No

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11
Q

OXIDATION
-What is an example of an oxidation reaction?

A

Dehydrogenation

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12
Q

HYDROGENATION
-Describe how to bonds change

A

You go from an alkene to an alkane

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13
Q

HYDROGENATION
-What happens here?

A

You break the double bond by adding 2 hydrogen atoms

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14
Q

What is the difference between hydration and hydrogenation?

A

In hydrogenation you add two hydrogens, while in hydration you are adding a water

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15
Q

REDUCTION
-What is this?

A

Gaining hydrogens or losing oxygens

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16
Q

REDUCTION
-What is an example of a reduction reaction?

A

Hydrogenation

17
Q

A carboxylic acid is made by the ____ of an aldehyde

18
Q

DECARBOXYLATION
-What happens here?

A

COOH is replaced by a hydrogen, becoming CO2 on the products side

19
Q

CONDENSATION REACTIONS
-What happens with these reactions?

A

You remove H from one molecule and OH from a different molecule, which will become water on the products side. Then join the molecules

20
Q

CONDENSATION REACTIONS
-Where do you remove H from?

A

oxygen or nitrogen

21
Q

CONDENSATION REACTION
-Where do you remove the OH from?

22
Q

ETHER CONDENSATION
-What is the equation for this?

A

alcohol + alcohol = ether + water

23
Q

ETHER CONDENSATION
-How do you do this?

A

Remove OH from one side and H from the other

24
**ESTERFICATION** -What type of reaction is this and what is the equation?
-Condensation reaction -carboxylic acid + alcohol = ester + water
25
**ESTERFICATION** -Describe what you do
Remove the H from the alcohol and the OH from the carboxylic acid
26
**AMIDATION** -What is the equation for this?
carboxylic acid + amine = amide + water
27
**AMIDATION** -What happens here?
You remove the H from the amine (NH2) and the OH from the carboxylic acid
28
**PHOSPHORYLATION** -What is the equation for this?
phosphoric acid + alcohol = phosphoester + water
29
**PHOSPHORYLATION** -What do you do here?
Remove the H from the alcohol and the OH from the phosphoric acid
30
**HYDROLYSIS** -What happens with these?
A large molecule reacts with water and breaks down into smaller ones
31
**HYDROLYSIS** -Hydrolysis is the opposite of what?
Condensation Reactions
32
**ETHER HYDROLYSIS** -What is the equation for this?
ether + water = alcohol + alcohol
33
**ETHER HYDROLYSIS** -Describe what happens here
You break up the oxygen and add OH to the carbon and H to the oxygen
34
**ESTER HYDROLYSIS** -What is the equation?
Ester + water = carboxylic acid + alcohol
35
**ESTER HYDROLYSIS** -Describe what happens here
1. Break the C-O bond 2. Add OH to carbon and H to oxygen
36
**AMIDE HYDROLYSIS** -What is the equation?
amide + water = carboxylic acid + amine
37
**AMINE HYDROLYSIS** -Describe what you do
1. Break the C-N bond CLOSEST to the carbonyl group 2. Add OH to the carbon and H to the nitrogen