Reactions Flashcards
Alochol
Primary alcohols oxidize to become aldehydes under the presence of hydrogen ions (H+) or dichromate ions (CR2O7 2-)
It becomes a carboxylic acid if heat is added.
Secondary alcohols oxidize to become keytones under the presence of (H+ / Cr2O7 2– / MnO4 – )
Tertiary alcohols do not oxidize because the carbon that the hydroxide is attached to is not connected to any hydrogens thus oxidation does not occur at that carbon
Ester creation
A carboxylic acid reacts with alcohol and forms an ester and water under the presence of H+ ions. The alcohol in the ester is the carbon chain directly connected to oxygen and the carboxylic acid is the carbon chain not connected to the oxygen. The alcohol becomes the branch whereas the carboxylic acid becomes the main chain. E.g. Propanoic acid + Methanol = Methyl Propanoate
Ionisation of water
Carboxylic acid + water = carboxylic acid ion + hydronium
Hydrolysis of esters
Ester + H2O → Carboxylic acid + alochol, needs heat as a catalyst
Carboxylic acid to amides
Primary Amide:
Carboxylic acid + Ammonia → …amide
e.g. Butanoic acid + Ammonia → Butanamide
Secondary Amide:
Carboxylic + …amine → … …amide
e.g. Butanoic acid + methylamine → 1 methyl butanamide
Reaction pathways
Alkane → Chloroalkane
Needs UV light and Cl2, subsitution
Chloroalkane → Alochol
s
Alkene → alochol
Needs H2O and heat