Reactions Flashcards

1
Q

Alkenes + H2

A

Nickel catalyst
150°C
Alkanes

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Alkenes + Halogen

A

Halogenoalkane

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Alkenes + Hydrogen Halides

A

Halogenalkanes

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Alkenes + steam (hydration)

A

Phosphoric acid
60 - 70 atm
300°C
Alcohol

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Oxidation of alkenes

A

Acidified Potassium Manganate

Diol

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Combustion of Alkenes

A

Incomplete

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Combustion of alcohols

A

Complete

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Chlorination (primary) alcohol

A

PCl5 used
Chloroalkane
POCl3
HCl

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Chlorination (tertiary) alcohol

A

HCl used
Shake it
Chloroalkane + Water

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Bromination of alcohol

A

KBr used
50% conc H2SO4
Warmed
HBr formed in situe

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Iodination of alcohols

A

Red phosphorus
Heat under reflux
PI3 produced in step 1

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Dehydration of alcohols

A

conc. H3PO4
Heat
Alkane

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Hydrolysis of halogenoalkanes

A
Hot KOH
50/50 mixture of water and ethanol
Heat under reflux
………………………………………………………..
AgNO3, HNO3
Ethanol
Warm in a water bath
………………………………………………………..
Warm
Water
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Halogenoalkanes with KCN

A

Ethanol

Heat under reflux

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Halogenoalkanes with ammonia

A

Heat in a sealed tube
2 steps:
1. NH3 nucleophile
2. NH3 base

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Elimination of halogenoalkanes

A

Hot KOH
Ethanol
Heat under reflux

17
Q

Nitration of benzene

A

conc HNO3
conc H2SO4
55°C

18
Q

Halogenation of benzene

A

Halogen carrier
AlCl3, FeBr3, FeCl3
Warm

19
Q

Alkylation of benzene

A

Alkyl chloride
AlCl3
Anhydrous

20
Q

Acylation benzene

A

Acyl chloride
AlCl3
Anhydrous

21
Q

Reduction of carbonyl

A

LiAlH4

Dissolved in dry ether

22
Q

Carbonyl with HCN

A

HCN -> with alkali catalyst
KCN
H2SO4