Definitions Flashcards

1
Q

Relative isotopic mass

A

The weighted average mass of one atom of an isotope compared with 1/12th of the mass of an atom of the isotope of carbon-12

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2
Q

Relative atomic mass

A

The weighted average mass of an element compared with 1/12th of the mass of an atom of carbon-12

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3
Q

First ionisation energy

A

The energy required to remove an electron from one mole of gaseous atoms to form one mole of gaseous +1 ions

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4
Q

Periodicity

A

A repeating trend or pattern across different periods

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5
Q

Orbital

A

A region where there is a high probability of finding an electron

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6
Q

Ionic bond

A

Electrostatic attraction between two oppositely charged ions

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7
Q

Covalent bond

A

Electrostatic attraction between two positive nuclei and a shared pair of electron

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8
Q

Electron pair repulsion theory

A

Electron pairs in the outer shell arrange themselves to maximise separation and minimise repulsion

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9
Q

Hydrogen bond

A

Intermolecular force of attraction between an electron deficient hydrogen (bonded to an element more electronegative than itself) and the lone pair of electrons on an electronegative atom in another molecule

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10
Q

Allotrope

A

Different forms of the same element in the same physical state

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11
Q

Electronegativity

A

The ability of an atom to attract a shared pair of electrons in a covalent

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12
Q

Instantaneous dipole-induced dipole interactions (London forces)

A

At a single point in time, the electron density around a molecule will not be symmetrical. One side has more electron density causing an instantaneous dipole and this induced a dipole in a nearby molecule which can attract to the instantaneous dipole

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13
Q

Disproportionation

A

When a single element is simultaneously oxidised and reduced in a single reaction

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14
Q

Empirical formula

A

The simplest whole number ratio of atoms of each element in a compound

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15
Q

Molecular formula

A

The actual number of atoms of each element in one molecule

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16
Q

Homologous series

A

A family of compounds which all contain the same functional group and each member of the series contains one more CH2 than the previous

17
Q

Functional group

A

Part of the molecule responsible for the chemical reaction

18
Q

Structural isomerism

A

Compounds with the same molecular formula but different structural and displayed

19
Q

Stereoisomerism

A

Molecules with the same structural formula but the atoms are arranged differently in a space

20
Q

Radical

A

Species with an impaired electron

21
Q

Electrophile

A

Electron pair acceptor

22
Q

Nucleophile

A

An electron pair donor

23
Q

Standard enthalpy change of reaction

A

Enthalpy change when the number of substances in the equation as written react (100kPa)

24
Q

Enthalpy change of formation

A

Enthalpy change when one mole of substances is formed from its constituent elements (100kPa)

25
Q

Enthalpy change of combustion

A

Enthalpy change when one mole of substance is completely in oxygen (100kPa)

26
Q

Enthalpy change of neutralisation

A

Enthalpy change when one mole of water is produced by neutralisation of an acid with a base (100kPa)

27
Q

Hess’s Law

A

Enthalpy change of a reaction is independent of the oath taken provided that the individual and final conditions are the same

28
Q

Bond enthalpy

A

Enthalpy change when one mole of a bond in the gaseous state is broken