Definitions Flashcards
Relative isotopic mass
The weighted average mass of one atom of an isotope compared with 1/12th of the mass of an atom of the isotope of carbon-12
Relative atomic mass
The weighted average mass of an element compared with 1/12th of the mass of an atom of carbon-12
First ionisation energy
The energy required to remove an electron from one mole of gaseous atoms to form one mole of gaseous +1 ions
Periodicity
A repeating trend or pattern across different periods
Orbital
A region where there is a high probability of finding an electron
Ionic bond
Electrostatic attraction between two oppositely charged ions
Covalent bond
Electrostatic attraction between two positive nuclei and a shared pair of electron
Electron pair repulsion theory
Electron pairs in the outer shell arrange themselves to maximise separation and minimise repulsion
Hydrogen bond
Intermolecular force of attraction between an electron deficient hydrogen (bonded to an element more electronegative than itself) and the lone pair of electrons on an electronegative atom in another molecule
Allotrope
Different forms of the same element in the same physical state
Electronegativity
The ability of an atom to attract a shared pair of electrons in a covalent
Instantaneous dipole-induced dipole interactions (London forces)
At a single point in time, the electron density around a molecule will not be symmetrical. One side has more electron density causing an instantaneous dipole and this induced a dipole in a nearby molecule which can attract to the instantaneous dipole
Disproportionation
When a single element is simultaneously oxidised and reduced in a single reaction
Empirical formula
The simplest whole number ratio of atoms of each element in a compound
Molecular formula
The actual number of atoms of each element in one molecule
Homologous series
A family of compounds which all contain the same functional group and each member of the series contains one more CH2 than the previous
Functional group
Part of the molecule responsible for the chemical reaction
Structural isomerism
Compounds with the same molecular formula but different structural and displayed
Stereoisomerism
Molecules with the same structural formula but the atoms are arranged differently in a space
Radical
Species with an impaired electron
Electrophile
Electron pair acceptor
Nucleophile
An electron pair donor
Standard enthalpy change of reaction
Enthalpy change when the number of substances in the equation as written react (100kPa)
Enthalpy change of formation
Enthalpy change when one mole of substances is formed from its constituent elements (100kPa)
Enthalpy change of combustion
Enthalpy change when one mole of substance is completely in oxygen (100kPa)
Enthalpy change of neutralisation
Enthalpy change when one mole of water is produced by neutralisation of an acid with a base (100kPa)
Hess’s Law
Enthalpy change of a reaction is independent of the oath taken provided that the individual and final conditions are the same
Bond enthalpy
Enthalpy change when one mole of a bond in the gaseous state is broken