Reaction Rates Flashcards
Heat of Reaction
the energy absorbed or released in a chemical equation
Exothermic Reaction
reactions that release energy
Endothermic Reaction
reactions that absorb energy
Activation Energy
the minimum energy needed for a reaction to take place
Reaction Rate
the change in concentration of reactants or products per unit time
Collision Theory
a model that explains reaction rate as the result of particles colliding with a certain minimum energy
Positive Catalyst
a substance that increases the rate of a chemical reaction without itself undergoing a permanent change
Potential Energy curve
Look at graph on page 1 of notes and learn the 9 labels
What is an Effective Collision
- reacting particles are correctly aligned when they collide
- reacting particles must have sufficient kinetic energy to break existing bonds
Factors effecting Reaction Rate [5]
- Nature of the substance
- Surface area of the substance
(greater SA means faster rate) - Concentration of the substance
(Increase in [ ] means a faster rate)
(Increase in pressure means an increase in [ ]) - Temperature
(higher temp means faster rate) - Use of a catalyst
Learn the EXPLANATIONS for each factor of reaction rate
page 2 of notes
Maxwell-Boltzmann Distribution Curve
- shows the number of particles able to go effective collisions
- increase in temperature causes the number of particles able to undergo effective collisions to increase
- redraw the curve
- curves must have same area under the line
- area under line = number of particles
- catalyst just pushes the minimum energy line closer to the origin (no redraw of curve!!)
Product vs Time Graphs
- reaction will always end at a certain point
(only so much can be produced) - reaction rate starts out fast and decreases over the course of the reaction
Reactant vs Time Graphs
- opposite shape to product graph
- graph can intercept x axis (meaning reactant is used up) or flatline above it (meaning that the other reactant is the limiting reactant)
- reaction rate starts out fast and decreases over the course of the reaction