Reaction Pathways Organic Flashcards

1
Q

Alkene to Alkane

A

H2 Nickel catalyst, heat 150 celcius

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2
Q

Alkene to Dihaloalkane

A

React with X2 at RTP, this is a test for unsaturation.

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3
Q

Alkene to Haloalkane

A

Hydrogen halide 20 celcius

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4
Q

Alkane to Haloalkane

A

Halogen and UV

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5
Q

Alkene to Alcohol

A

H3PO4 steam high temp and pressure

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6
Q

Alcohol to Alkene

A

Conc.H3PO4 or H2SO4 heat

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7
Q

Haloalkane to Alcohol

A

NaOH, H20 and heat under reflux

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8
Q

Alcohol to Haloalkane

A

Sodium halide, H2SO4

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9
Q

Primary Alcohol to aldehyde (CHO)

A

K2Cr2O7 and H2SO4 in distilation

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10
Q

Aldehyde (CHO) to Primary alcohol

A

NaBH4 and water

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11
Q

Primary Alcohol to carboxylic acid (COOH)

A

K2Cr2O7 and H2SO4 heat and reflux

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12
Q

Aldehyde to Carboxylic acid

A

K2Cr2O7 and H2SO4 in reflux

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13
Q

Alcohol to Ester

A

Carboxylic acid and Conc. H2SO4 OR acid anhydride OR acyl Chloride

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14
Q

Carboxylic acid to Ester

A

Alcohol and Conc. H2SO4

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15
Q

Ester to Carboxylic acid

A

Dilute acid heat and dilute alkali in reflux

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16
Q

Ester to Carboxylate

A

OH- and heat

17
Q

Carboxylic acid to Acyl Chloride

A

SOCl2

18
Q

Acyl Chloride to carboxylic acid

A

Cold water

19
Q

Acyl chloride to primary Amide

A

20 Celsius and NH3

20
Q

Acyl chloride to secondary amide

A

Primary amine at 20 Celcius

21
Q

Haloalkane to Nitrile

A

NaCN/KCΝ in reflux with ethanol

22
Q

Nitrile to Amine

A

H2 and Ni

23
Q

Haloalkane to Amine

A

excess ethanolic ammonia and heat

24
Q

Nitrile to carboxylic acid

A

Dilute HCL water, heat in reflux

25
Q

Alcohol to Ketone

A

K2Cr2O7 and H2SO4 under reflux

26
Q

Ketone to secondary Alcohol

A

NaBH4 and water

27
Q

Ketone to hydroxynitrile

A

HCN

28
Q

Aldehyde to Hydroxynitrile

A

HCN

29
Q

Hydroxynitrile to Amine

A

LiAH4 and dilute acid

30
Q

Acyl Chloride to Ester

A

Alcohol and 20 celcius