Reaction Pathways Organic Flashcards by Hugo Wells

Q

Alkene to Alkane

A

H2 Nickel catalyst, heat 150 celcius

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Q

Alkene to Dihaloalkane

A

React with X2 at RTP, this is a test for unsaturation.

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Q

Alkene to Haloalkane

A

Hydrogen halide 20 celcius

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Q

Alkane to Haloalkane

A

Halogen and UV

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Q

Alkene to Alcohol

A

H3PO4 steam high temp and pressure

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Q

Alcohol to Alkene

A

Conc.H3PO4 or H2SO4 heat

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Q

Haloalkane to Alcohol

A

NaOH, H20 and heat under reflux

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Q

Alcohol to Haloalkane

A

Sodium halide, H2SO4

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Q

Primary Alcohol to aldehyde (CHO)

A

K2Cr2O7 and H2SO4 in distilation

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Q

Aldehyde (CHO) to Primary alcohol

A

NaBH4 and water

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Q

Primary Alcohol to carboxylic acid (COOH)

A

K2Cr2O7 and H2SO4 heat and reflux

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Q

Aldehyde to Carboxylic acid

A

K2Cr2O7 and H2SO4 in reflux

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Q

Alcohol to Ester

A

Carboxylic acid and Conc. H2SO4 OR acid anhydride OR acyl Chloride

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Q

Carboxylic acid to Ester

A

Alcohol and Conc. H2SO4

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Q

Ester to Carboxylic acid

A

Dilute acid heat and dilute alkali in reflux

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Q

Ester to Carboxylate

A

OH- and heat

Q

Carboxylic acid to Acyl Chloride

A

SOCl2

Q

Acyl Chloride to carboxylic acid

A

Cold water

Q

Acyl chloride to primary Amide

A

20 Celsius and NH3

Q

Acyl chloride to secondary amide

A

Primary amine at 20 Celcius

Q

Haloalkane to Nitrile

A

NaCN/KCΝ in reflux with ethanol

Q

Nitrile to Amine

A

H2 and Ni

Q

Haloalkane to Amine

A

excess ethanolic ammonia and heat

Q

Nitrile to carboxylic acid

A

Dilute HCL water, heat in reflux

Alcohol to Ketone

K2Cr2O7 and H2SO4 under reflux

Ketone to secondary Alcohol

NaBH4 and water

Ketone to hydroxynitrile

HCN

Aldehyde to Hydroxynitrile

HCN

Hydroxynitrile to Amine

LiAH4 and dilute acid

Acyl Chloride to Ester

Alcohol and 20 celcius