Reaction Pathways Flashcards

1
Q

reaction between haloalkane and alkene

A

elimination through:
- conc. strong base
- ethanol solvent
- reflux - heat

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2
Q

reaction between haloalkane and dihaloalkane

A

substitution

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3
Q

reaction between haloalkane and nitrile

A

substitution through:
- KCN dissolved in ethanol
- heat-reflux

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4
Q

reaction between haloalkane and amine

A

substitution through:
- excess NHa dissolved in ethanol
- heat - reflux

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5
Q

reaction between alkene and alkane

A

reduction through:
- adding hydrogen H2
- metal catalyst
- Pd, Pt, Ni

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6
Q

reaction between alkene and polyalkene

A

addition through:
- catalyst
- heat
- pressure

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7
Q

reaction between alkene and alcohol

A

addition through:
- add water
- strong acid catalyst
- heat, pressure

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8
Q

reaction between alkane and haloalkane

A

substitution through:
- halogen X2
- UV light or high temp.

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9
Q

reaction between alkene and dihaloalkane

A

addition through:
- add halogen X2

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10
Q

reaction between alkene and haloalkane

A

addition through:
- adding hydrohalogen H-X

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11
Q

reaction between nitrile and amine

A

reduction through:
- LiAIH4 with water or
- H2 with heat, pressure, metal catalyst Pd, Pt, Ni

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12
Q

reaction between alcohol and primary and secondary

A

oxidation

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13
Q

reaction between alcohol and carboxylic acid

A

condensation

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14
Q

what is produced during alcohol to carboxylic acid reaction?

A

condensation esterification:
- carboxylic acid & alcohol
- strong acid catalyst
- heat

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15
Q

reaction between secondary alcohol and ketone

A

oxidation through:
- warm acidified (O)
- e.g. K2Cr2O7, KMnO4

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16
Q

reaction between aldehyde and carboxylic acid

A

oxidation through:
- warm acidified (O)
- e.g. K2Cr2O7, KMnO4

17
Q

reaction between amine and carboxylic acid

A

condensation through:
- carboxylic acid & amine
- heat

18
Q

what is produced between amine and carboxylic acid reactions?

A

Amide

Acidic condition:
- strong acid
- heat
- produces carboxylic acid, amine salt

Basic conditions:
- strong base
- heat
- produces amine, carboxylic salt

19
Q

reaction between primary alcohol and aldehyde

A

oxidation through:
- warm acidified (O)
- e.g. K2Cr2O7, KMnO