reactants and test 4 Flashcards
Hg(OCOCH3)2 in THF followed by NaBH4 in OH
oxymercuration forms an alcohol
BH3 in THF followed by H2O2 in OH
non markovnikov alcohol
H2 Pd
alkane
H2 lindlar catalyst
cis alkene
RCO3H in CH2Cl2
epoxides from alkane (RCO3H peroxy…)
O3 followed by Zn in weak acid or H2O2 in acid
2 ketones from a trisubstitued alkene
OsO4 followed by NaHSO3 in water
cis diol
na cold nh3
trans alkene
NaNH2 in liquid NH3
forms an alkyne or chain elongation
Br2 or Cl2 in FeBr3 or FeCl3
adding a Br or a Cl to a ring
HNO3 in H2SO4
add NO2 to a ring
H2 in Pd or Fe,H3O+ followed by OH *****
on a ring, reduction of an acyl substituent so going from CHOCH2CH3 to CH2CH2CH3
SO3 in H2SO4
add SO3 to a ring, sulfonation
cold NaOH then hot NaOH then H3O+ **
R-CL with AlCl3
friedel craft, carbon chain on a ring add
RCOCl with AlCl3
acetylation, adding c chain with a double bond o to a ring, like friedel craft
KMnO4 in water
changing an R chain of a ring to a COOH
Mg in THF followed by H2O ***
remove a br or a cl
NaBH4 in H2O
changing a c=o to a cooh
LiAlH4 in ether followed by H3O+
changing a carboxylic acid to a primary OH
SOCl2 in organic base
changing a primary alcohol to a primary alkyl halide
good with primary and secondary alcohols but bad with tertiary alcohols
PBR3 PCl3
change alcohol to Br or Cl
good with primary and secondary alcohols but bad with tertiary alcohols
H3PO4 or H2SO4 with heat ***
make an alkene from alcohol
really difficult with primary, must be very very hot
ok with secondary alcohol much less heat
good with tertiary alcohol
CrO3 with water and sulfuric acid (Jones)
1 alc to carboxylic acid
2 alc to kenone