Rates of reaction & Energy changes Flashcards

1
Q

How does surface area effect rate (marble chip practical)

A

Smaller chips = larger surface area = faster rate of reaction

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2
Q

How does increasing the concentration of hydrochloric acid effect rate (marble practical)

A

Grater concentration = grater number of particles in a given volume = faster rate

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3
Q

How is rate of reaction determined through reactants formed

A

​amount​ ​of​ ​reactant​ ​used​ / time

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4
Q

How is rate of reaction determined through products formed

A

amount of product formed / time

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5
Q

How do you measure reactant used

A

if product is a gas, which will be given off, you can carry out the reaction on a set of weighing scales and measure
how much mass is lost

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6
Q

How do you measure product formed

A

if product is a gas, you can measure the volume of gas produced in a gas syringe

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7
Q

What is activation energy

A

the minimum amount of energy required for a chemical reaction to occur

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8
Q

How do reactions occur

A

When reacting particles collide with enough energy

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9
Q

How can you increase the rate of rection

A
  • temperature
  • pressure
  • concentration
  • surface area
  • using a cataylst
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10
Q

How does increasing temperature increase rate of reaction

A

Increasing temperature = increasing kinetic energy of particles
Collide more frequently and energetically, more likely to reach activation energy

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11
Q

How does increasing pressure increase rate of reaction

A

Increases the number of particles in a given volume therefore increases frequency of collisions

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12
Q

How does increasing concentration increase rate of reaction

A

increases the number of particles in a given volume and so increases the frequency of collisions

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13
Q

How does increasing surface area increase rate of reaction

A

There is a greater chance of particles colliding, increases the frequency of successful collisions therefore increases the rate of reaction

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14
Q

How do you find the rate of reaction graphically

A

Draw tangents to curves and use the slope of the tangent as a measure of
the rate of reaction

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15
Q

What does the gradient equate to

A

rate of reaction

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16
Q

What is a catalyst

A

Substances that speed up chemical reactions without being used up

17
Q

How do catalysts increase the rate of a reaction in terms of activation energy

A

Catalysts decrease the activation energy by
providing a different pathway for a chemical reaction allowing for more successful collisions

18
Q

How are enzymes used in the production of alcoholic drinks

A

Yeast is the enzyme used in the production of ethanol as it is fermented from
sugars

19
Q

What kind of reaction is a neutralisation reaction

A

Exothermic

20
Q

What kind of reaction is a precipitation reaction

A

exothermic

21
Q

What kind of reaction is salts dissolving in water

A

either exothermic or endothermic

22
Q

What kind of reaction is a displacement reaction

A

Either endothermic or exothermic

23
Q

What is required when these reactions (changes in heat energy) take place in a solution

A

carry them out in a
polystyrene cup with a lid, and measure the temperature change using a
thermometer

24
Q

What is an exothermic reaction

A

transfers energy to the surroundings so the temperature of the surroundings increases

25
Q

Give examples of exothermic reactions

A
  • combustion
  • many oxidation reactions
  • neutralisation
26
Q

What is an endothermic reaction

A

takes in energy
from the surroundings so the temperature of the surroundings decreases.

27
Q

Give examples of endothermic reactions

A
  • thermal decomposition
  • reaction of citric acid & sodium hydrogen carbonate.
  • sport injury packs
28
Q

What is the process of breaking bonds and why

A

Endothermic -energy must be suppled to break bonds

29
Q

What is the process of making bonds and why

A

Exothermic - energy is released when bonds are formed

30
Q

What is the overall heat energy change for an exothermic reaction

A

Energy taken in to break < energy released when formed (overall energy has been released)

31
Q

What is the overall heat energy change for an endothermic reaction

A

Energy taken in to break > energy released when formed
(because overall energy has been taken in)

32
Q

How to calculate the energy change in a reaction given the energies
of bonds

A

Sum of energy taken in to break bonds – sum of energy released to form bonds =
overall energy change

33
Q

Why may a reactions energy change be negative

A

energy out is more than energy in

34
Q

What is activation energy

A

minimum amount of energy that particles must
have to react

35
Q

Describe a reaction profiles for exothermic diagram

A

The products have less energy than the reactants and energy has been released to the surroundings

36
Q

Describe a reaction profiles for endothermic diagram

A

reactants have less energy than the products because the energy has been taken in from surroundings