rates of reaction (4.1) Flashcards

1
Q

when can a chemical reaction only happen

A

when the reactant particles collide with enough energy

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2
Q

what is the amount of energy particles need to react called

A

activation energy

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3
Q

what does the overall rate of reaction spend on

A

the collision frequency
percentage success

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4
Q

what is a collision frequency

A

how often do the particles collide with each other

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5
Q

what is a percentage success

A

what percentage of the collisions have enough energy

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6
Q

what are the four factors that effect rate of reaction

A

surface area
concentration
temperature
catalysts

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7
Q

why does a higher solid surface area increase rate of reaction

A

more of the solid is exposed to the other particles
so the collision frequency is higher
so there are more successful collisions per unit time

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8
Q

why does increasing temperature increase rate of reaction

A

the particles have more kinetic energy
so the percentage of collisions with enough energy is higher
so there are more successful collisions per unit time

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9
Q

why does having a higher concentration/pressure increase rate of reaction

A

there are more particles per unit volume
so the collision frequency is higher
so there are more successful collisions per unit time

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10
Q

why do catalysts increase rate of reaction

A

they provide an alternative route with a lower activation energy
so the percentage of collisions with enough energy is higher
so there are more successful collisions per unit time

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11
Q

what experiment shows the effect of surface area with rates of reaction

A

the marble chip experiment

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12
Q

what is the marble chip experiment

A

reacting calcium carbonate (marble) with hydrochloric acid

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13
Q

indépendant variable of the marble chip experiment

A

sizes of CaCO3(s) chips

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14
Q

dependant variable of the marble chip experiment

A

volume of CO2(g)

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15
Q

control variable of marble chip experiment

A

mass of CaCO3(s)
volume and concentration of HCL(aq)
temperature

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16
Q

results of marble chip experiment

A

faster beginning because the rate is increased, so the volume of CO2 is increasing faster
same final volume brace the amount of reactants hasn’t changed, so the experiment produces the same amount of CO2

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17
Q

what experiment is used to show how concentration effects rate of reaction

A

disappearing cross experiment

18
Q

what is the disappearing cross experiment

A

reacting sodium thiosulphate solution with hydrochloric acid

19
Q

independent variable of disappearing cross experiment

A

concentration of the NaS2O3 (sodium thiosulphate solution)

20
Q

dependent variable of disappearing cross experiment

A

time taken for cross to disappear

21
Q

control variables for disappearing cross experiment

A

total volume of solution
concentration of HCL(aq)
temperature

22
Q

1 rate =

A

collision frequency x percentage success

23
Q

how is rate calculated in the disappearing cross experiment

A

rate = 1/time taken (s)

24
Q

what does the disappearing cross experiment show

A

rate is proportional to concentration
double the concentration = double the rate
triple the concentration = triple the rate etc

25
what experiment is used to show how temperature effects rate of reaction
magnesium and acid experiment
26
what is the magnesium and acid experiment
when you react magnesium(s) with hydrochloric acid(aq)
27
indépendant variable for magnesium and acid experiment
temperature of HCL(aq)
28
dependant variable for the magnesium and acid experiment
time taken for the Mg(s) to disappear
29
control variable for the magnesium acid experiment
mass and surface area of MG(s) volume and concentration of HCL(aq)
30
how is rate calculated in the magnesium and acid experiment
rate = 1/time taken (s)
31
what does the magnesium acid experiment show
rate isn't proportional to temperature
32
what are catalysts
substances that increase rate and remain chemically unchallenged
33
how do catalysts work?
they provide an alternate route with a lower activation energy so the percentage of collisions with enough energy is higher so there are more successful collisions per unit time
34
what experiment shows the effect of catalysts with rate of reaction
hydrogen peroxide experiment
35
what is the hydrogen peroxide experiment
the decomposition of hydrogen peroxide
36
what is the catalyst used in the hydrogen peroxide experiment
manganese(IV) oxide (mnO2)
37
what does manganese oxide do in the hydrogen peroxide experiment
it makes a reaction that usually takes days to finish, take only a few seconds to finish
38
independent variable in the hydrogen peroxide experiment
what catalyst is being used
39
dependent variable of the hydrogen peroxide experiment
volume of O2
40
control variables in the hydrogen peroxide experiment
volume and concentration of H2O2(aq) temperature mass and surface area of the catalyst
41
what does the hydrogen peroxide experiment show
more effective catalysts increase rate more effectively