Rates Of Reaction Flashcards
Increasing Temperature
Increases KE
More collisions per unit volume
More successful collisions per unit time
Rate of Reaction increases
Increasing Concentration
More particles per unit volume
Collision frequency is higher
More successful collisions per unit time
Rate of reaction increases
Increase Surface area
more solid is exposed to other particles
Collision frequency is higher
More successful collisions per unit time
Rate of reaction increases
What does a catalyst do?
A catalyst provides an alternative route with a lower activation energy
Add a catalyst
Frequency of collisions with enough energy is higher
More successful collisions per unit time
Rate of Reaction increases
Practical: Reacting Sodium thiosulphate with Hydrochloric acid
Aim: To determine the effect of concentration on rate of reaction
Independent variable - concentration of sodium thiosulphate
Dependent variable - Time take for cross to disappear
Control variables - temperature, concentration of HCl, volume of the solution
Observations - solid sulphur is produced, black cross gradually disappears
How is rate calculated?
Rate = 1/ time taken
Practical: Reacting calcium carbonate chips with Hydrochloric acid
Aim: To determine the effect of surface area on the rate of reaction
Independent variable - size of calcium carbonate chips
Dependent variable - volume of CO2 produced
Control variables - mass of calcium carbonate, volume and concentration os HCl, temperature
Observations - calcium carbonate chips dissolve in Hydrochloric acid
Equation:
CaCO3 + 2HCl —> CaCl2 + H2O + CO2
Practical: Reacting Magnesium with Hydrochloric acid
Aim: to determine the effect of temperature on the rate of reaction
Independent Variable: Temperature of HCl
Dependent Variable: time taken for Mg (s) to disappear
Control Variable: Mass and SA of Mg, volume and concentration of HCL
Observations:
Magnesium solid dissolves
What do catalysts do?
Increase rate of reaction
Remain chemically unchanged
Practical: Decomposition of Hydrogen Peroxide
Aim: to determine the effect of ac catalyst on the rate of reaction
Catalyst is magnesium oxide - black solid
Catalyst are not included in equation because they are unchanged during the reaction
Independent variable: Catalyst being used
Dependent Variable: Volume of Oxygen produces
Control Variable: Volume and Concentration of Hydrogen peroxide, temperature, mass and surface area of catalyst
Equation:
2H2O2 —> 2H2O + O2