Rates and Energy Flashcards
What are three ways that you could do a rate of reaction experiment?
- Precipitation reaction (the time it takes for a precipitate to form)
- Mass change (change in mass over time)
- Volume of gas ( given off during a time period, for a reaction)
Rate of reaction equation?
amount of reactants used or amount of product formed / time
How do you carry out the marble chip experiment?
- Place marble chips in a flask with a dilute hydrochloric acid
- Place a syringe on top of the flask and attach it to the flask, making sure that everything is air-tight.
- Start the timer as the reaction happens and stop it at regular intervals, measuring the volume of gas captured each time.
- Do the same experiment with the same amount of everything but this time crush the chips.
What conclusion can you draw from the marble chips experiment? (About the surface are of a reactant)
The finer the chips (bigger) the sooner the reaction finished, meaning that this was the fastest reaction time.
What other factors can increase the reaction rate in the marble chip experiment? (Most other reaction) (Other than surface area and temperature)
Increasing the concentration of the hydrochloric acid.
How is sodium thiosulphate and hydrochloric acid practical performed?
- Mix both mixtures into a conical flask
- Place the conical flask on black spot
- Measure the time it takes for a precipitate to form and cloud your vision towards the black spot. (This is the reaction time)
- Try at different temperatures to see how that effect the reaction time.
What factors does the rate of reaction depend on?
Temperature
Surface area
Concentration
Pressure (gases)
What factors affect collisions?
collision frequency
Energy transferred at each collision
What is activation energy?
What is the two meaning?
The minimum amount of energy particles needs when they collide, for a reaction to start.
The minimum amount of energy needed for bonds to break.
How does increasing temperature increase reaction?
- Particles have more kinetic energy and thus move around more. (More collisions = more reaction)
- More energy is transferred in collisions
How does increasing concentration (or pressure) increase reaction?
- More particles with a volume mean that more collisions can occur.
- In a gas increasing pressure means particles are more crowded and more collisions can occur.
How does an increase in the surface area affect the reaction rate?
-Particles will have more areas to collide with and transfer energy which means that the rate of reaction will increase.
How do catalysts work and increase the rate of reaction?
They provide an alternative path for a reaction that requires lower activation energy.
What are the 4 main reactions that are exothermic?
salt dissolving in water
Precipitation
Displacement
Neutralisation
Is bond-breaking Exo or endo?
Exothermic