Rate Process In Chemical Reactions Flashcards

1
Q

What’s a spontaneous reaction?

A

Rxn that occurs without any further help or input

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2
Q

A spontaneous reaction (which happens on its own) go from what energy state?

A

A reaction to happen on its own needs to be High energy (unstable) to go to low energy (stable)

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3
Q

What’s a rate limiting step in a chemical reaction?

A

It is the slowest step in a reaction that delays the rate of overall reaction ie. everything else

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4
Q

What’s equilibrium?

A

When the rate of forward reaction is same as the rate of reverse reaction

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5
Q

Thermal energy

A

Heat energy

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6
Q

Thermal energy

A

When atoms have kinetic energy. Something cold i.e. low thermal energy and something hot i.e. high thermal energy

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7
Q

What are the forces that can cause potential energy?

A

Potential energy is possesed by an object due to its position and it can be caused by:
- Gravitational forces
- Nuclear forces
- Electromagnetic forces

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8
Q

What happens when an object moves in same direction as force?

A

Potential energy is released and turned into kinetic energy

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9
Q

What happens when an object moves in opposite direction as force?

A

Object stores the potential energy

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10
Q

Negative change in energy system

A

When heat is transferred from system to the surroundings

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11
Q

Positive change in energy system

A

When heat is transferred from the surrounddings to the systems

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12
Q

Negative change in energy

A

System expands (work is done by system in surrounding)

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13
Q

Positive change in energy

A

System compressed (work is done on system by the surrounding)

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14
Q

Net energy equation

A

Delta U = Heat (q) - work (W)

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15
Q

What’s Enthalpy?

A

Sum of all the internal energy (kinetic and potential) in the system

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16
Q

Breaking bonds

A

Requires energy as a molecule is going from stable to unstable

17
Q

Forming bonds

A

Releases energy as it goes from unstable to stable

18
Q

Endothermic reactions cause

A

Positive enthalpy change as energy is being absorbed and thermal energy of system decreases

19
Q

Exothermic Reaction

A

Negative enthalpy change as energy is being released and thermal energy of system increases

20
Q

Entropy (measure of disorder) is positive when?

A

System moves towards more disordered state

21
Q

Entropy (measure of disorder) is negative when?

A

System moves toward less disordered state

22
Q

Is it easier for chemical reactions to increase entropy or decrease it?

A

Increasing entropy is easier as they proceed to be more disordered

23
Q

What’s Gibbs free energy?

A

Energy available overall considering the enthalpy and entropy of the system

24
Q

What’s the equation for Gibbs energy?

A

🔺G = 🔺H - T🔺S

🔺G < 0: spontaneous rxn in forward direction

🔺G > 0: nonspontaneous rxn in forward direction

🔺G = 0: rxn is at equilibrium