Rate Of Reaction Flashcards
What is the average rate of a reaction
The total change in concentration of reactants/products divided by the time taken for the reaction to take place
What is instantaneous rate
The rate of change occurring at a specific time in the reaction
How to find instantaneous rate
Find gradient of tangent at point
What must a property be to find the rate by dividing rate of change of property by time
Must be proportional to concentration as og equation was change in concen/time
What is the rate of reaction
Measures the rate of formation of a product/ rate of removal of a reactant
Two reasons why a reaction may get faster as it progresses
-if it is exothermic and the temperature rises
-if the reaction gives a product that can act as a catalyst for the reaction
Experimental techniques to determine rate of reaction
-measure change in colour using colorimeter
-change in mass if gas produced (must be sufficiently dense or the change in mass is too small to measure on balance)
-volume of gas produced
Methods to measure concentration changes
-quench reaction using sodium hydrogen carbonate and titrate with sodium thiosulfate and starch indicator
-measure electrical conductivity
-change in colour using colorimetry
How to find initial rate of reaction
Draw tangent at t=0 and find the gradient of this tangent
How to construct and use a calibration curve
Involves using a colorimeter to measure absorbance of solutions of known concen from which a calibration curve is plotted, then absorbance of sample from reaction mixture can be measured and calibration curve used to convert absorbance readings into concentration values