Rate & Extent of Chemical Change Flashcards

1
Q

What are the two equations for mean rate of reaction?

A

Mean Rate of Reaction= Quantity of used Reactant/Time

Mean Rate of Reaction= Quantity of Product/Time

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2
Q

What is the unit for rate of reactions?

A

g/s, mol/s or cm³/s

As product or reactant can be measured in mass or volume or moles.

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3
Q

Which factors affect the rate of reactions?

A

Concentration(solution), Pressure(g), Surface Area(s), temperature and catalysts.

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4
Q

What is collision theory?

A

The theory explaining how chemical reactions occur.

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5
Q

How do chemical reactions occur?

A

When two reacting particles collide with each other with sufficient energy to react. This energy is the activation energy.

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6
Q

What is the activation energy?

A

The minimum energy for particles to collide and react.

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7
Q

How does concentration, pressure and surface area increase the rate of reaction?

A

This increases the frequency of collisions and thus the rate of reaction is increased due to the increased number.

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8
Q

How does increasing the temperature increase the rate of reaction?

A

The particles collide more frequently as the particles move further. The collisions are also more energetic and thus a greater number of sufficiently energised collisions occur.

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9
Q

Why is surface area to volume ratio important?

A

An object with a greater surface area to volume ratio will react completely faster.

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10
Q

What are catalysts?

A

Particles which change the rate of reaction but are not used up.

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11
Q

What are biological catalysts?

A

Enzymes

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12
Q

How do catalysts function?

A

They provide a pathway of reduced activation energy to increase the rate of reaction.

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13
Q

What is a reversible reaction?

A

A chemical reactions in which the products can to react to form the reactants.

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14
Q

How can some reactions be reversed?

A

Changing conditions (heat for example) the energy released and absorbed is equal in both reactions.

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15
Q

What is it when reversible reactions reach equilibrium?

A

When, in closed apparatus- where products cannot escape, the rate of reaction for forward and reverse reactions occur at the same rate- they are equal.

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16
Q

How does concentration in a system affect the equilibrium?

A

Reactants or products will react in inverse to the concentration to find an equilibrium with the same number of moles in each solution.

17
Q

How does temperature in a system affect the equilibrium?

A

If temperature increases:
Endothermic products increase
Exothermic products decrease
and vica-versa.

18
Q

How does pressure in a system affect the equilibrium?

A

Increased pressure shifts equilibrium towards the products with the fewest molecules and vica-versa.