Raman Sped Flashcards
What happens in Raman spec
Light from an incident laser source is inelastically scattered and shows up as a shift in frequency.
The energy associated with this shift of frewucny is that of a molecular vibration.
What is elastic scattering
An amount of energy hits a sample and Bounces off. There is no interaction byeeeen matter and photon.
What is a inleasttic scattering
Energy hits sample and sample uses soem fo the energy to do a molecular vibration , the energy associated with it changes . The wavelength therefore changes as some of the energy has been used to set the molecule into vibstyion mode.
What is on the spectrum
Intensity v wavelength differnce
Dif fence between ir and Raman
Light hitting sample in Raman is much higher In energy and on,y some of the energy is absorbed
Advantages of Raman over ir
Minimal sample prep
Very general - Can be applied on a lot of materials
Rich in information
Aqueous samples can be easily used.
Disadvantages of Raman over ir
Effect is weak - v sensitive detectors needed - expensive.
Interference from fluorescence - can swamp Raman signal