Quantum Part 1 Flashcards
What is the intensity of a black body?
I=σT^4
What is Wien’s displacement law?
λmaxT=a constant=2.898x10^-3Km
What is the power of a black body?
I=σAT^4
What is the wavelength for a standing wave?
λn=2L/n
What is Rayleigh-Jeans law?
For a 3D black body I(λ)=(2πck_B T)/λ^4
What is the ultraviolet catastrophe?
Where for small λ the black body curve no loner follows the Rayleigh-Jeans law
How is energy quantised?
En=nhf
What is Planck’s model for the intensity?
I(λ,T)=(2πc^2 h)/λ^5 * 1/((e^(hc⁄(λk_B T)))-1)
I(λ,T)=(2πc^2 h)/λ^5 * <E>
I(T)=(2π^5k_B^4 T^4)/(15h^3c^2)</E>
What is the average energy of a black body?
hf/(e^βhf-1)
What is the average energy for high T?
kBT= hf/βhf
What is the average energy for low T?
hf/e^βhf =hfe^(-hf/(k_B T))
What is the work function?
How much energy is required to remove an electron from a surface
KE=hf-Φ
What is the relativistic energy?
E^2=p^2c^2+m_0^2c^4
What is the energy of a photon?
m_0=0 so E=pc=hf
What is the momentum of a phton?
p=h/λ
How much is one angstrom?
1A_o=10^-10m
What is the change in λ for Compton scattering?
Δλ=h/mc*(1-cosθ) where θ is the angle of scattering
What is the Compton wavelength?
h/mc=λ_C=0.024 Angstroms =2.4x10-12m
What is the maximum change in λ for Compton scattering?
2λ_C=0.05 angstroms
What is the minimum change in λ for Compton scattering?
0
For what range is Compton scattering significant?
For x-rays (0.1 to 100) angstroms in λ
What is the Rydberg formula?
1/λ=R(1/m^2-1/n^2) where m<n
With R=1.097x10^7m^-1
What is the Rydberg formula involving the atomic number?
1/λ=RZ^2`(1/m^2-1/n^2)
What is the Bohr radius?
a_0= roughly 0.5 angstroms
What radius orbits are allowed for electrons orbiting the nucleus?
r_n=n^2a_0
What is the quantised angular momentum?
L_n=nħ=m_e x v_n x r_n
Where ħ=h/2π
What are the energy levels for a hydrogen atom?
E_n=-13.6eV/n^2
What is the de Broglie wavelength?
λ=h/p
What is the quantum momentum?
p=h/λ=ħk
What is Bragg’s law?
nλ=2dsinθ
What is the wave particle duality?
The wave description and particle description are complementary and both are required to model the nature properly
What is the from of the TDSE?
(-ℏ^2)/2m (∂^2 φ)/(∂x^2 )=iℏ ∂φ/∂t
When is the plane wave a solution to the TDSE?
When ℏω(k)= ℏ^2k^2/2m
What is the probability of finding a particle between two points a and b at a time t?
∫|φ(x,t)|^2 dx
Integrated between a and b
What is the form of the normalisation condition?
|φ|^2=∫|φ(x,t)|^2 dx=1
What is a wave packet?
If φ1 and φ2 are solutions then φ= Aφ1+Bφ2 is also a solution
The superposition of many plane waves with wave numbers grouped around an average value k_0
What is the form of a plane wave?
φ=Aexp(i(kx-ωt))
What is Heisenberg’s uncertainty principle?
ΔxΔp≥ℏ/2
ΔEΔt≥ℏ/2
What is the distribution for a wave packet centred around k_0?
Ψ=∫dx a(k)exp(i(kx-ω(k)t))
What is the width of the wave packet in k?
w
What is the width of the wave packet in s?
1/w
What is w for a wave packet?
w=2σ√2ln2
What is the form of the TISE?
(-ℏ^2)/2m (∂^2 Φ)/(∂x^2 )+VΦ=EΦ
For the equation iℏ dP/dt=Ep has solution p(t)=e^((-iEt)⁄ℏ)
What is the probability density?
|φ|^2
What is a stationary state?
Where energy is constant and does not change with time as the probability density is independent of time due to p being a phase term.
E= ℏω is constant
For a particle in an infinite potential well what is the wave equation?
Φ=(2/L)^1/2b sin(nπx/L)
What does k^2 equal to?
k^2=2mE/ℏ^2
What does the energy equal to for a plane wave related to k?
En=(ℏ^2 k^2)/2m=(ℏ^2 n^2 π^2)/(2mL^2 )
For a quantum particle what is necessary for the boundary condtions?
ψ(x) and dψ(x)/dx must be continuous at x=0 and x=L
For a finite potential barrier what is the transmission probability?
T= (FF)/(AA ) for quantum tunnelling where E<V0
T= (BB)/(AA ) for reflection where E>V0
What is the transmission probability related to?
T ∝ e^(-2k_2 L) ∝ e^((-2L√(2m(V-E)))/ℏ)
As k2=-ik’=√(2m(V-E))/ℏ
What is the half life?
t^1/2=half life=ln(2)/λ
What is the decay rate?
λ =decay rate=number of attempts at the barrier per second times T
Ln λ =C2-C1(Z-2)/√(E_k )