Quantitative Chemistry Flashcards

1
Q

What does the Law of Conservation of Mass state?

A

No matter is lost or gained during a chemical reaction.

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2
Q

In a balanced chemical equation, what must be true about the mass of reactants and products?

A

The total mass of the reactants is equal to the total mass of the products.

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3
Q

What is a precipitation reaction?

A

A reaction in which two solutions react to form an insoluble solid called a precipitate.

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4
Q

What happens to the mass of a reaction flask if a gaseous product escapes?

A

The total mass of the reaction flask will change as product mass is lost.

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5
Q

True or False: The total amount of matter before and after a reaction is the same.

A

True

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6
Q

If there is no subscript number after an element in a chemical formula, what does it signify?

A

There must be one of that particular element.

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7
Q

What does a subscript number after brackets indicate in a chemical formula?

A

That number belongs to all the elements inside the bracket.

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8
Q

Which non-metals must be written as molecules?

A
  • H2
  • N2
  • O2
  • F2
  • Cl2
  • Br2
  • I2
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9
Q

How do you balance a chemical equation?

A

Ensure the same number of atoms of each element on both sides of the equation.

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10
Q

What is the relative atomic mass symbol?

A

Ar

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11
Q

What does the symbol Mr refer to?

A

The total mass of the molecule.

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12
Q

How do you calculate the relative formula mass (Mr) of a substance?

A

Add up the relative atomic masses of all the atoms present in the formula.

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13
Q

What is the formula to calculate the percentage by mass of an element in a compound?

A

% mass of an element = (r × number of atoms of the element) / Mr of the compound × 100

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14
Q

What is the equation for percentage composition?

A

Percentage Composition = (total mass of element / mass of compound total) × 100

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15
Q

True or False: The total mass of a reaction flask will decrease if a gaseous product escapes.

A

True

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16
Q

What happens to the mass of the reaction flask when a metal reacts with oxygen?

A

The mass of the oxide produced is greater than the mass of the metal you started with.

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17
Q

What is produced when metal carbonates thermally decompose?

A

Carbon dioxide gas

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18
Q

What type of error occurs due to faulty experimental procedures?

A

Systematic errors

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19
Q

What is the difference between random errors and systematic errors?

A

Random errors vary in direction, while systematic errors always pull results in the same direction.

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20
Q

What is the uncertainty for a thermometer that reads to 1°C?

A

+0.5°C

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21
Q

How is uncertainty calculated for digital instruments?

A

The uncertainty is taken as the smallest division on the scale.

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22
Q

What is the uncertainty for an electronic balance that reads to 0.01 g?

A

+0.01 g

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23
Q

How can uncertainty in results be estimated from repeated experiments?

A

Uncertainty is ± half of the range of results.

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24
Q

Fill in the blank: Uncertainty can arise from __________ judgment of the experimenter.

A

subjective

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25
What is a common source of uncertainty in titration experiments?
Judging the end point by looking at the color of the indicator.
26
What should be done when uncertainties are difficult to quantify?
Comment on them as a source of error in an evaluation.
27
What is the mole and its symbol?
The mole, symbol mol, is the SI unit of amount of substance.
28
How many particles are in one mole of a substance?
One mole contains 6.02 x 10^23 particles, known as the Avogadro Constant.
29
What does one mole of sodium (Na) contain?
One mole of sodium contains 6.02 x 10^23 atoms of sodium.
30
What does one mole of hydrogen (H2) contain?
One mole of hydrogen contains 6.02 x 10^23 molecules of hydrogen.
31
What is the mass of 1 mole of a substance called?
The mass of 1 mole of a substance is known as the molar mass.
32
How is the molar mass of an element determined?
For an element, it is the same as the relative atomic mass written in grams.
33
How is the molar mass of a compound determined?
For a compound, it is the same as the relative molecular or formula mass in grams.
34
What is the formula for converting between moles, mass, and molar mass?
The formula is: Moles = Mass / Molar Mass.
35
What can chemical/symbol equations be used to calculate?
They can be used to calculate the moles and mass of reactants and products.
36
What is the process to balance a chemical equation using masses?
Convert masses to moles, find the molar ratios, and then write the balanced equation.
37
True or False: One mole of any element is equal to the relative atomic mass of that element in grams.
True.
38
Fill in the blank: The mass of a substance can be calculated using the formula _______.
Mass = Moles x Molar Mass.
39
What do you need to do if the resulting numbers from mole calculations are uneven?
Multiply all of the numbers by the same number to find the smallest whole number for the coefficients.
40
How do you calculate the number of moles for an element?
Divide the mass of each element by its relative atomic mass (Ar) ## Footnote For example, for hydrogen: 10 g / Ar(H) = 10.
41
What is a limiting reactant?
The reactant that is used up first in a reaction, limiting the amount of product formed.
42
What happens to the reaction when the limiting reactant is completely used up?
The reaction cannot continue.
43
What is a solute?
A solid substance that dissolves in a liquid.
44
What is a solvent?
The liquid in which a solute dissolves to form a solution.
45
What does concentration refer to?
The amount of solute in a specific volume of solvent.
46
What is the formula for calculating concentration?
Concentration (g/dm³) = mass of solute (g) / volume of solution (dm³)
47
1 dm³ is equivalent to how many cm³?
1000 cm³
48
How do you convert from cm³ to dm³?
Divide by 1000.
49
How do you convert from dm³ to cm³?
Multiply by 1000.
50
What is yield in the context of a chemical reaction?
Yield is the term used to describe the amount of product you get from a reaction.
51
Why is it rare to achieve 100% yield in a chemical process?
* Some reactants may be left behind in the equipment * The reaction may be reversible * Products may be lost during separation and purification * Side reactions may occur * Products can be lost during transfer
52
What is the difference between actual yield and theoretical yield?
* Actual yield: recorded amount of product obtained * Theoretical yield: amount of product that would be obtained under perfect conditions
53
What does the percentage yield compare?
The percentage yield compares the actual yield to the theoretical yield.
54
What is the equation to calculate percentage yield?
percentage yield = (actual yield / theoretical yield) × 100
55
If a student prepared 1.6 g of copper(II) sulfate while the theoretical yield is 2.0 g, what is the percentage yield?
Percentage yield = 80%
56
What are the steps to calculate theoretical masses of products?
* Write out the balanced equation * Convert the given mass of reactant(s) into moles * Use the coefficients in the equation to deduce moles of product(s) * Convert moles of product into mass
57
In the reaction Zn + CuSO4 → Cu + ZnSO4, if 6.5 g of zinc is added, how many moles of zinc does it yield?
0.1 mol
58
What is the maximum mass of copper that could be formed from 0.1 moles of zinc?
6.35 g
59
What is atom economy?
Atom economy studies the amount of reactants that get turned into useful products.
60
What is the formula for calculating atom economy?
Atom economy = (total Mr of desired product / total Mr of all reactants) × 100
61
Calculate the atom economy for the reaction CH4 + H2O → CO + 3H2.
17.6%
62
What factors should companies consider when choosing a reaction pathway?
* Atom economy * Percentage yield * Rates of reaction * Equilibrium position
63
True or False: High percentage yields and fast reaction rates are desirable attributes in industrial chemical processes.
True
64
What can improve the atom economy of a reaction?
Selling or reusing waste products.
65
Fill in the blank: The actual yield and percentage yield can only be determined by _______.
[experiment]
66
What is one common error when calculating percentage yield?
Dividing the theoretical yield by the actual yield instead of the other way around.