Quantitative Chemistry Flashcards

1
Q

State the law of conservation of mass

A

No atoms are lost or made during a chemical reaction so total mass of products = total mass of reactants

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2
Q

In experiment, how can you easily compare mass of products with reactants?

A

Add up the mass of all the containers and the reactants and do the same with the products and their containers

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3
Q

When might the total mass of products appear to be more than the reactants?

A

If a gas reacts and its particles enter the container

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4
Q

When might the total mass of products appear to be less than the reactants?

A

If a gas is formed and the particles leave the container

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5
Q

What is the symbol for relative formula mass?

A

Mr

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6
Q

How is relative formula mass calculated?

A

It is the sum of the relative atomic masses of all atoms in the formula

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7
Q

How does relative formula mass relate to conservation of mass in a balanced symbol equation?

A

Sum of relative formula masses of reactants = sum of the relative formula masses of the products

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8
Q

In experiments, how can you calculate uncertainty?

A

Uncertainty = Range/2

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9
Q

To how many decimal places should uncertainty be quoted?

A

The same number as the data used to calculate it

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10
Q

What is the unit for mole?

A

mol

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11
Q

Define a mole

A

The mass of one mole of a substance in grams is numerically equal to its relative formula mass

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12
Q

The mole is a constant numerical value called the Avogrado constant, what is this number?

A

6.02 x 10(23)

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13
Q

What is the equation that links moles to amount of substance and Avogrado’s constant?

A

Moles = amount of substance / 6.02x 10(23)

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14
Q

What is the equation that links moles to mass and relative formula mass?

A

Moles = mass / Mr

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15
Q

What are the three steps involved in calculating an unknown mass in a balanced symbol equation?

A
  1. Use n = M x Mr to calculate moles
  2. Use the molar ratio to find moles of unknown
  3. Use M = n / Mr to calculate unknown mass
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16
Q

What is the common error made when completing a reacting mass calculation?

A

Balancing numbers are used when calculating Mr

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17
Q

How are kg’s converted into grams?

A

Divide by 1,000

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18
Q

How are tons converted into grams?

A

Divide by 1,000,000

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19
Q

How do balancing numbers relate to moles?

A

They give us the molar ratio of all substances in the reaction

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20
Q

If given masses, how can you calculate molar ratios?

A
  1. Use moles = M/Mr
  2. Use the molar ratio to find moles of unknown
  3. Convert to whole numbers by multiplying through
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21
Q

What does excess reactant mean?

A

More of the reactant is used than is required

22
Q

Why add a reactant to excess?

A

To ensure all the limiting reactant is used up

23
Q

What does limiting reactant mean?

A

A reactant that is completely used up limiting the amount of product

24
Q

When performing chemical calculations, should limiting or excess reactant be used?

A

Limiting reactant

25
How can you determine which reactant is in excess?
Calculate the moles of both reactants then compare to the molar ratio
26
At room temperature, what is the value of the molar gas volume?
24 dm(3)
27
What is the equation linking volume of gas and moles?
moles = volume / 24
28
What unit should volue have in the molar gas equation?
dm(3)
29
What is the most common unit of volume?
cm(3)
30
How can you convert cm(3) into dm(3)?
/ 1000
31
Describe the strategy for finding an unknown volume of gas in a reaction
1. calculate moles using n = v/24 2. use molar ratio to find moles of unknown 3. calculate volume of unknown using v = n x 24
32
What are the units of concentration?
mol/dm(3) or g/dm(3)
33
What is the equation for calculating concentration from moles?
concentration = moles / volume
34
What is the most common unit for volume?
cm(3)
35
What unit of volume is required for calculating concentration?
dm(3)
36
How can you convert cm(3) into dm(3)?
/ 1000
37
What is the equation for calculating concentration from mass?
concentration = mass/ volume
38
How can you convert mol/dm(3) into g/dm(3)?
x Mr
39
How can you calculate the mass of solute when given concentration and volume?
mass= concentration x volume x Mr
40
How is the mean titration volume calculated?
By adding up the concordant results and dividing by the number of concordant results
41
Describe the strategy for finding an unknown concentration in titration
1. calculate moles using n = C x v 2. use molar ratio to find moles of unknown 3. calculate concentration of unknown using C= n/V
42
Why is it not possible to obtain 100% yield?
Reaction might be reversible. Products are lost during separation. Reactants react in unexpected ways
43
What is yield?
The amount of product obtained
44
How can you calculate % yield?
% yield = (actual mass/ theoretical mass) x 100
45
What is atom economy?
A measure of the amount of starting materials that end up as useful products
46
Why is high atom economy important?
Sustainable development and for economic reasons
47
How can you calculate atom economy?
Atom economy = (Mr desired product / Mr of all reactants) x 100
48
What is unusual about calculating atom economy?
The balancing numbers are used when calculating all the Mr's
49
How can atom economy be improved?
By finding a use for the waste products
50
What is the atom economy for a reaction where only one product is made?
100%