Qualitative Tests for Organic Compounds Flashcards
For alkenes
Bromine
Baeyer’s
For alkyl halides
Beilstein
For alcohols
Lucas
For phenols
Ferric chloride
For aldehydes, alcohols, and other reducing compounds
Jones Oxidation
Fehling’s
For aldehydes and ketones
Brady’s
For methyl ketones only
Iodoform
For amines
Hinsberg
Reagent of Bromine
Bromine in CCl4
Reagent of Baeyer’s
KMnO4
Reagent of Beilstein
Copper wire with sample
Flame
Reagent of Lucas
Zinc chloride in HCl
Reagent of Ferric Chloride
FeCl3
Reagent of Jones Oxidation
Chromic acid in sulfuric acid
Reagent of Fehling’s
Fehling’s A: cupric sulfate
Fehling’s B: Na K tartrate
Reagent of Brady’s
2,4-dinitrophenylhydrazine
Reagent of Iodoform
Alkaline iodine solution
Reagent of Hinsberg
Benzenesulfonyl chloride
Result of Bromine
Disappearance of orange
Result of Baeyer’s
Disappearance of violet
Formation of brown ppt
Result of Beilstein
Green flame
Result of Lucas
Tertiary: cloudiness faster
Secondary: cloudiness slower
Primary: no reaction
Result of Ferric chloride
Blue or purple
Result of Jones Oxidation
Green
Result of Fehling’s
Brick red ppt
Result of Brady’s
Red ppt
Result of Iodoform
Pale yellow ppt
Result of Hinsberg
Primary: soluble product
Secondary: insoluble product
Tertiary: no reaction