QM fundamentals Flashcards
Hermitian operator
Adaggar = A
Can move A over WF w/o gaining -
evals of Hermitian operator
Always real
evects/efuncs of Hermitian operator
Form a complete orthogonal basis for H (L^2(R)) square integrable functions
Observables represented by
Hermitian operators
Position operator
$x\hat \psi = x \psi$
Momentum operator
$p \hat \psi = \frac{h}{i} \frac{d}{dx} \psi(x)$
Fundamental commutation relation in QM
x\hat and p\hat do NOT commute!
what is [x\hat,p\hat] =
i h
are x\hat and p\hat hermitian
Yes
kinetic energy operator
p\hat ^2 /2m
Note p\hat ^2 \psi = p\hat (\frac{h}{i} \frac{d}{dx} \psi(x))
=-h^2 \frac{d^2}{dx^2}
thus
\frac{p\hat ^2}{ 2m} \psi (x) = -\frac{h^2}{2m} \frac{d^2}{dx^2} \psi (x)
H\hat \psi (x) =
(K\hat +V\hat) \psi(x)
=[ -\frac{h^2}{2m} \frac{d^2}{dx^2} \psi (x) + V(x) ] \psi (x)
What does the hamiltonian operator represent
The systems total energy
SUm of the the kinetic and potantial energy operators acting of \psi (x)
What is an operator
A ‘recipie’ for tunring one WF into another via a combination of differentiaiton(wrt x) and multiplication (of x and scalar constants)
What hapeneds during a measurement of a WF
state of system collapses from linear combination or a single eigen state. (with with meausred eval) this step is irreversible
state will well defiend values of O are what
eigen states of O\hat
Since a measurement of O will yeild (with prob = 1) the eiegen value associated wiht that estate