P334 fundamentals Flashcards
what does sueprpositibility impose on WE
wave equation must obey a linear eqn, turns out it is the SE,
Debroglie hypothesis
p = h k
Where did SE derived from
Reflecting the dispersion relation expeced using E = h omega and de broglie (p = hk
What is the EOM in quantum mechanics
E
w/ normalisation also imposed
General fautire of normalisability
Makes surface integral dissapeak
Can the expectation val be time dep
Yes
p in 3d is ?
p_op = -i h nabla
Hermitian operators associated with what LA
Matrices
Expepactation values
i.e. Integrals over obsevable w/ wf’s in QM are akin to what in LM
matix elements of matrices (where matrix is the observable itself)
Correspondence principle of QM
- observables are represented by hermitian operators (that act on WF)
- calssical relations hold for expectation values
(also Bohr’s corr principle)
Bohr’s correspondence principle
Classical relation hold for large quantum numbers (energies)
Moving the derivative over results in what
an extra minus
Derivative is anti-hermitian