Production Of Polyethylene Flashcards
LDPE polymerisation process
Peroxide initiator splits, forming free RADICALS, which allow the INITIATION of ethylene monomers.
LDPE requirements
1,000-3,000 atmospheric pressures.
High temperature 300°C.
Initiator - Organic peroxide.
Initiator perixide
Is not a catalyst as it gets incorporated into polymer.
Branching of LDPE polymer formed:
Chain branching.
Cannot be compact or be packed in orderly way.
Molecular weight of molecules formed:
Up to 1,000,000 g/mol.
Recycling symbol:
/ 04 \
\ PE-LD /
HDPE process name:
Zeigler-Natta process.
HDPE requirements:
Pressure of a few (3) atmospheres.
60°C
A catalyst.
HDPE polymerisation process
Occurs on surface of catalyst.
Branching of HDPE polymer formed
UNBRANCHED PE molecules that are able to pack closely in an orderly fashion.
Molecular weight of HDPE molecules formed:
Up to 3,000,000 g/mol
HD-PE recycling symbol
02 \
PE-HD \