Princeton Course Test 3 Flashcards
spring constant equation
1/2kx^2
what do intermolecular attractions do?
- increase the potential energy between molecules, decreasing their kinetic energy
what comes along with increasing size and number of electrons?
- greater polarizability, which increases strength of London’s dispersion forces
what are the only two amino acids with 4 oxygen atoms?
- aspartic acid
- glutamic acid
when weak acids are put into solution
- only partially ionized
- will not result in equal production of water molecules compared with strong acid/strong base
membrane transport is mediated by
- proteins
- not phospholipids
how to recognize a tautomer
- look for a shift in the atoms
if the second step is slow, what does that tell us about the activation energy?
- that the activation energy of the first step should be much greater than for the second step.
role of catalysts
- lower the activation energy
- do not affect the stability of intermediates in a reaction
the kinetics of any reaction
- can only affect the rate of the reaction
the thermodynamics of any reaction
- affect results based on stability.
thin layer chromatography
- uses small amounts of material to determine polarity of compounds and monitor reactions
- think thin and less
ionization of sulfuric acid
- after the loss of the first proton, the remaining hydrogen is bound to a negatively-charged molecule.
- electrostatic attraction between this remaining hydrogen and the negatively-charged molecule would disfavor loss the second proton, resulting in a smaller k.
what is resistivity
- resistivity of a current-carrying component immediately implies dissipation of heat
power is defined as
W/t
thyroid hormone
- T3 and T4
- is a peptide but acts like a steroid
cells that have not completed meiosis I are
- diploid
primary oocytes are arrested in which phase
- prophase I
synapsis
- the bringing together of homologous chromosomes during meiosis I so that crossing over can occur.
can amino acids cross the placental and fetal capillary membranes
- no
- they are charged
do maternal and fetal blood mix during pregnancy
- no!
how can a substance cross the placental barrier
- if it is lipid soluble or if it is actively transported