Polymers Flashcards

1
Q

Chemical compounds with large molecules bonded together in long, repeating chains.

A

Polymers

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2
Q

Sequentially bonding repeating units in polymers.

A

Monomers

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3
Q

Polymers offer physical properties such as _____ and _____ that can be desirable in a wide range of uses.

A

Strength, Elasticity

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4
Q

Polymers properties can be _____ or _____ to a greater degree (compared to metals or other classes of materials).

A

Controlled, Tailored

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5
Q

Interactions between chains of a polymer lead elements of _____ to the structure of polymers.

A

Order

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6
Q

Stretching the polymer chains as they form can _____ the amount of order, leading to a degree of crystallinity of the polymer.

A

Increase

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7
Q

_____ the polymer chains lead to a degree of crystallinity of the polymer.

A

Stretching

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8
Q

Different degree of _____ can lead to polymers of the same substance that have very different physical properties.

A

Crystallinity

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9
Q

Chemically bonding chains of polymers to each other can _____ and _____ the substance.

A

Stiffen, Strengthen

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10
Q

The average number of repeating units in the polymer chain.

A

Degree of Polymerization

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11
Q

Product of the degree of polymerization and the molecular weight of the repeating unit.

A

Molecular Weight of a Polymer

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12
Q

Polymers in which the chains fold and make lamellar structure arranged in the regular manner.

A

Crystalline Polymers

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13
Q

Polymers in which the chains are in the irregular manner.

A

Amorphous Polymers

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14
Q

A state when the amorphous region of the polymer is at lower temperature.

A

Glassy State

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15
Q

When a polymer is in glassy state, it is
_____ , _____ , and ______.

A

Brittle, Hard, Rigid

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16
Q

A state when the polymer is heated.

A

Rubbery State

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17
Q

When a polymer is in rubbery state, it becomes _____ and _____.

A

Soft, Flexible

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18
Q

Temperature at which glassy state makes a transition to rubbery state.

A

Glass Transition Temperature (Tg)

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19
Q

Glass Transition Temperature (Tg) is a property of the _____ materials, or the amorphous region of a ______ materials.

A

Amorphous, Semicrystalline

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20
Q

Amount of stress required to break the sample.

A

Strength

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21
Q

Measures the percentage change in the length of the material before fracture.

A

Percent Elongation to Break (Ultimate Elongation)

22
Q

Measures the stiffness of the material.

A

Young’s Modulus (Modulus of Elasticity or Tensile Modulus)

23
Q

_____ polymers are polymers that occur naturally and exists in living things in nature.

24
Q

_____ polymers are man-made polymers made in laboratory through chemical processes.

25
The types of polymer (based on the structure of their monomer chain) are _____ , _____ , and _____.
Linear, Branched, Cross-Linked
26
The types of polymers are _____ , _____ , and _____.
Thermoplastics, Thermosetting Polymers, Elastomers
27
Polymers that melt or deform on heating. (can be repeatedly soften by heating and then solidifies by cooling)
Thermoplastics
28
Molecules in a thermoplastic are held together by relatively _____ intermolecular forces.
Weak
29
Polymers that offer increased strength upon heating, and will retain their form and stay solid even under heat.
Thermosetting Polymers
30
Polymers that can be stretched easily to several times their length and which rapidly return to their original dimensions when the applied stress is released.
Elastomers
31
The process of creating synthetic polymers by combining small monomer molecules into chains held together by covalent bonds.
Polymerization
32
In _____ polymerization, small monomer units joined to form a giant polymer.
Addition
33
Addition polymerization begins with the generation of a _____ , which is normally accomplished by heating a molecule.
Free Radical
34
In addition polymerization, the free radical repeatedly attacks the _____ bond in a monomer molecule, forming a new radical that now includes one monomer unit.
Double
35
In _____ polymerization, it involves the elimination of a small molecule, usually water, as each monomer is added to the growing chain.
Condensation
36
In condensation polymerization, there must be two _____ groups on the monomer, which can react together to form small molecules.
Functional
37
Condensation polymers are made by joining two subunits through a reaction in which a smaller molecule (often water) is also formed as a by-product. These are also called _____.
Copolymers
38
_____ copolymers are arranged in a regular, alternating series.
Alternating
39
_____ copolymers has regions in the material where a single monomer unit is repeated, interspersed with other regions where a different monomer is the repeating unit.
Block
40
In block copolymers, some regions are relatively _____ , whereas others are _____.
Stiff, Flexible
41
_____ copolymers involve side chains of one polymer attached to a backbone of a different polymer.
Graft
42
In graft copolymers, both _____ and _____ are attached to a _____ backbone.
Butadiene, Acrylonitrile, Polystyrene
43
A thermoplastic made from monomer ethylene. It is soft, flexible and melts at a low temperature.
Low-Density Polyethylene (LDPE)
44
A thermoplastic made from petroleum. It has a higher chemical resistance and can withstand higher temperature.
High-Density Polyethylene (HDPE)
45
Thermoplastic polymer used in various applications due to its good chemical resistance.
Polypropylene (PP)
46
The third-most widely produced plastic that is cheaper and stronger than traditional alternatives such as copper or ductile iron.
Polyvinyl Chloride (PVC)
47
An aromatic polymer made from the monomer styrene, it has very slow biodegradation
Polystyrene (PS)
48
A family of synthetic polymers known genetically as polyamides.
Nylon, Nylon 6, Nylon 66
49
The amide backbone present in nylon causes it to be more _____ unlike hydrocarbon polymers.
Hydrophilic
50
Synthetic fluoropolymer of tetrafluoroethylene.
Teflon (Polytetrafluoroethylene)
51
Thermoplastic elastomer consisting of linear segmented block copolymers.
Thermoplastic Polyurethanes (TPU)
52
Plastic with the lowest coefficient of friction.
Teflon (Polytetrafluoroethylene)