Polymers Flashcards

1
Q

Which polymers are easiest to deform?

A

Linear polymers with weak intermolecular forces.

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2
Q

Does heat treatment work on polymers?

A

No.

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3
Q

What are plastics?

A

Plastics are organic materials with high molecular weight.

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4
Q

What are the types of plastic?

A

Thermosetting and thermoplastic.

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5
Q

What are some examples of thermosetting polymers?

A

alkyl resin, silicon resin)

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6
Q

What are some examples of thermoplastic polymers?

A

polyethene, polyester

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7
Q

What are some advantages of plastic?

A

Light, strong, low melting points, good shock absorbers, insulators, chemically inert, corrosion and water resistant.

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8
Q

What are some disadvantages of plastic?

A

Deformed under load, degrade upon extended

exposure to heat and UV.

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9
Q

What is the monomer of PVC?

A

Vinyl Chloride

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10
Q

What are elastomers (rubber)?

A

Rubbers are non-crystalline in nature and are high polymers that have elastic properties.

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11
Q

How many types of rubber are there?

A

2: Natural and synthetic.

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12
Q

What is corrosion?

A

Corrosion can be defined as any process of destructive disintegration or alteration of a metal or alloy caused by direct chemical attack or by electrochemical reaction with its environment.

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13
Q

What is dry corrosion?

A

This type of corrosion occurs through direct
chemical action of the environment or atmospheric gases such as oxygen, halogen, H2S, SO2, N2 or anhydrous inorganic liquids in close
contact with the metal

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14
Q

What is wet corrosion?

A

The conducting electrolytic liquid is in

contact with metal and two dissimilar metals are partially dipped in the electrolyte.

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15
Q

What are polymers?

A

Polymers are generally macromolecules formed by the repeated linking of a large number of small molecules. Can be organic or inorganic.

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16
Q

What is the structural unit of a polymer?

A

Structural unit of a polymer that combines together in a repeated fashion.

17
Q

What is polymerization?

A

Polymerization is a process in which a large number of small molecules combine to form a bigger molecule.

18
Q

What is degree of polymerization?

A

The number of repeating units or monomers present in a polymer chain is known as degree of polymerization

19
Q

What are Oligo polymers?

A

They are polymers with a low degree of polymerization

and have a 500–5000 molecular mass range.

20
Q

What are high polymers?

A

They are polymers with high degree of polymerization

and have a 10,000–2,00,000 molecular mass range.

21
Q

What is a homopolymer?

A

If the polymer consists of identical monomers, it is a homopolymer.

22
Q

What is a hetropolymer?

A

If the polymer consists of different types monomers, it is a hetropolymer or copolymer.

23
Q

What are the types of polymerization?

A
  1. Chain growth polymerization
  2. Condensation / Stepwise polymerization
  3. Co-polymerization
  4. Coordination polymerization.
24
Q

What is addition polymerization?

A

It is a reaction that yields a polymer which is an exact multiple of the original monomeric molecule.

25
Q

What is condensation polymerization?

A

This reaction involves the condensation of two functional groups present in the same kind of monomer or different kind of monomers by the elimination of small molecules

26
Q

What is copolymerization?

A

Co-polymerization is the joint polymerization of two or more different monomeric species.

27
Q

What is coordination polymerization?

A

Coordination or stereospecific polymerization involves directing the monomers in their approach to the growing polymer chain. Most often coordination polymerization is conducted using a catalyst. Involves initiation, propagation and term.

28
Q

What are the properties of polymers?

A

Strength, plastic deformation, crystallinity, chemical resistance.

29
Q

What does the strength of a polymer depend on?

A

Van der Walls forces, Covalent bonding, Chain length, slipping power.

30
Q

What is slipping power?

A

Resistance to slip and consequent deformation of a polymer, and slipping power mainly depends on shape of the molecule.

31
Q

What are amorphous polymers?

A

Polymers with long chains and bulky side

groups of low degree of symmetry. Weak intermolecular forces and flexible structure.

32
Q

What are crystaline polymers?

A

Linear chains allow a regular structure with increased intermolecular forces of attraction that lead to increased strength.

33
Q

What is Chemical resistance?

A

The chemical resistance of a polymer is decided by the nature of monomeric units and their molecular arrangement. Chemical attack causes softening, swelling and loss of strength of material.