Polymerization & Curing Lights Flashcards
What does a photo-initiator in resin do?
- Absorbs photon energy
- Combines with activator (amine)
- Creating free radicals
- Initiates polymerization via monomer (Bis GMA)
What is Comphorquinone?
- Photoinitiator
- Most common photo-absorbing material
- Maximum sensitivity is in the BLUE RANGE
- 400-520 nm
- Peak at 468 nm
What is the first step of Polymerization?
Initiation
- Production of reactive free radicals
- Chemical, light, heat
What is the second step of Polymerization?
Propagation
- Monomer units
- Polymer network
- 50-60% degree of conversion
What is the last step of Polymerization?
Termination
What are some different energy sources for curing lights? Which one do we use?
- Halogen
- Plasma-arc
- Argon laser
- LED (WHAT WE USE!)
What does LED stand for?
Light Emitting Diode
What is the spectrum of an LED curing light for camphorquinone?
430-490 nm
What are some perks of using an LED curing light?
- Long lasting light source
- Minimal bulb aging
- Shock resistant
- Less lateral heat production
- Efficient
- Cordless
What are 2 different photoinitiators other then CQ?
PPD & TPO - VIOLET SPECTRUM
They use LESS yellow than comphorqinone
Less the CQ… 398 nm and 381 nm respectively
What is neat about third generation LED lights?
- They are Dual-Emission Spectrum
- Reportedly cures all photo-initiated materials
What is Attenuation of Violet Light?
- Decreases as thickness of composite increases
- Fill particles tend to scatter more light at shorter wavelengths
What type of curing light do you use?
- Dual-Spectrum LED
- Bluephase G2 by Ivoclar
- 10 mm diameter fiber-optic light guide
- Soft start polymerization available
- Low or high setting (650 or 1200 mW)
What are the effects of INCREASED light exposure?
- Increased depth of cure
- Increased conversion (polymerization)
- Increased hardness
- Only up to a threshold…
What are the effects of DECREASED light exposure?
Inadequate polymerization