Polymerer2 Flashcards
Newtons law of viscosity, illustration and units
Lösblad
Newtonian fluids
constant viscosity, ex:luft,vatten .
Non-newtonian fluids. Vad är det och exempel
Förändrar viscosity beroende på flödeshastighet, ex:ketchup,blod
Viscosity
Vätskans motstånd mot flöde. Hur seg vätskan är.
Everything flows, Deborah
De=t deformation/ t återhämtning
Fundamental concepts of polymer melt flow. Amourphous and semi-crystalline polymer structure in melt phase?
Disordered random molecular orientation. All polymers are amorphous in melten state.
Fundamental concepts of polymer melt flow. Polymers are viscoelastic when deformed in the melt state, how different deformations? What is viscoelastic?
Small/slow deformation-> no change in orientation
Large/fast deformation->molecular orientation in the flow direction.
viscous part-molecular friction between molecules
elastic part-polymers förmåga att få tillbaka ursprunglig form
What are the flow characteristics of polymers in the melt stage?
-Thermoplastic polymers, shear thinning, the viscosity function, what causes thinning?
the viscosity function=Låg skjuvning(långsamt flöde)=högre viscositet(mer strukt. molekyler som motverkar flödet.)
+tvärt om.
——
what causes shear thinning=molekulär orientering , molekylär friktion.(mindre friktion=>lägre viskositet)
What are the flow characteristics of polymers in the melt stage?
-The melt flow index as measure of flowability how its measured
Sample heated in barrel, weight.
-The weight of the polymer in g extruded during 10 min test=MFI.
(Högt=mer lättflytande)