Polarity & Bonds & Molecular Geometry Flashcards

1
Q

Dipole

A

a molecule with a slightly positive end and slightly negative end

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2
Q

Dipole dipole force

A

the intermolecular force between the positive end of one molecule to the negative end of another molecule

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3
Q

intermolecular forces

A

forces that act between molecules

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4
Q

intramolecular forces

A

forces that act in molecules

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5
Q

london dispersion forces

A
  • weakest
  • temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles
  • between non polar molecules & noble gas molecules
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6
Q

molecular size affect on dispersion forces

A

more elections = bigger atomic radius = larger electron cloud = larger distance for electrons to move = larger temporary dipole = higher boiling point

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7
Q

molecular shape affect on dispersion forces

A

longer chained = greater electron movement = more closely packed electrons = greater attractive forces = larger temporary dipole = higher boiling point

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8
Q

dipole dipole interactions

A
  • strongest
  • between two polar molecules
  • occurs when a partially positive end of a molecule interacts with the partially negative end of a molecule
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9
Q

what’s a rule for dipole dipole interactions to occur

A

molecules must be around the same size- have about he same number of electrons

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10
Q

hydrogen bonding

A
  • dipole actions that occurs between molecules that have a hydrogen atom bonded to a highly electronegative atom
  • either fluorine, oxygen, or nitrogen
  • occurs when the partially positive end of hydrogen attracts the partially negative end of F, O, or N
  • these compounds have high boiling points
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11
Q

what is responsible for the strength of hydrogen bonding

A
  • big EN difference so great polarity

- close approach of dipoles because hydrogens extremely small size

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12
Q

dipole induced dipole interactions

A
  • between a polar molecules and a non polar molecule

- the polar molecule induces polarity in the non polar molecule

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13
Q

ion dipole interaction

A
  • exists between a polar molecule and an ion
  • Several polar molecules work together on one ion to slowly break up the lattice
  • Make bonds called “ion-dipoles”
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14
Q

what is responsible for a high boiling point

A

-strong intermolecular forces

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15
Q

permanent dipole

A
  • occurs when two atoms have a high electronegativity difference
  • a polar molecule has a permanent dipole
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16
Q

what is a polar molecule

A

a molecule that unequal charge distribution throughout its orbital

17
Q

what is a characteristic of a polar molecule

A

water soluble

18
Q

what is a characteristic of a non polar molecule

A

fat soluble