Polarity & Bonds & Molecular Geometry Flashcards
Dipole
a molecule with a slightly positive end and slightly negative end
Dipole dipole force
the intermolecular force between the positive end of one molecule to the negative end of another molecule
intermolecular forces
forces that act between molecules
intramolecular forces
forces that act in molecules
london dispersion forces
- weakest
- temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles
- between non polar molecules & noble gas molecules
molecular size affect on dispersion forces
more elections = bigger atomic radius = larger electron cloud = larger distance for electrons to move = larger temporary dipole = higher boiling point
molecular shape affect on dispersion forces
longer chained = greater electron movement = more closely packed electrons = greater attractive forces = larger temporary dipole = higher boiling point
dipole dipole interactions
- strongest
- between two polar molecules
- occurs when a partially positive end of a molecule interacts with the partially negative end of a molecule
what’s a rule for dipole dipole interactions to occur
molecules must be around the same size- have about he same number of electrons
hydrogen bonding
- dipole actions that occurs between molecules that have a hydrogen atom bonded to a highly electronegative atom
- either fluorine, oxygen, or nitrogen
- occurs when the partially positive end of hydrogen attracts the partially negative end of F, O, or N
- these compounds have high boiling points
what is responsible for the strength of hydrogen bonding
- big EN difference so great polarity
- close approach of dipoles because hydrogens extremely small size
dipole induced dipole interactions
- between a polar molecules and a non polar molecule
- the polar molecule induces polarity in the non polar molecule
ion dipole interaction
- exists between a polar molecule and an ion
- Several polar molecules work together on one ion to slowly break up the lattice
- Make bonds called “ion-dipoles”
what is responsible for a high boiling point
-strong intermolecular forces
permanent dipole
- occurs when two atoms have a high electronegativity difference
- a polar molecule has a permanent dipole