plant biochem: secondary products Flashcards
basic or primary products
occur in all plant cells and are necessary for cell or organism survival
secondary products
usually found only in specialized, differentiated cells and are produced in relatively small amounts
- not necessary for cell survival but benefit the plant
- important medicinally
- they often are physiologically active and/ or have psychoactive effects
plants produces diversity of chemically complex secondary products
utilizing biosynthetic pathways
- serve many functions in plants: detoxifiers, neutralizing waste prods and toxins
- provide a chemical defence against herbivores, insect pests, fungal bacterial and viral pathogens and even other plants
- some are attractants, luring flower pollinators and fruit disperses with desirable colours and scents
many of the secondary products produced by plants and fungi are pharmacologically active
they may serve as hormones, anti-cancer agents, antibiotics, narcotics, stimulants, depressants, antihistamines, hallucinogens, poisons and pesticieds
three major groups
alkaloids
terpenoids
phenolics
alkaloids
contain N-usually in a heterocyclic ring
- many bitter-tasting and toxic, making it likely they evolved as anti-herbivore and antibiotic defenses
- a large number of plant alkaloids are pharmacologically active, many have med application, while others are poisonous or hallucinogenic
terpenoids
- plant hydrocarbons
- built from 2-5 C isoprene units
- many scented volatile or essential oils and have med and antibiotic properties
- terpenoid glycosides are organic compounds consisting of sugars attached to non sugar terpenoids (aglycones)
- cardiac glycosides- stimulating effect on the heart
- saponin or steroidal glycosides, yield mammalian hormone precursors
phenolics
- aromatic ring to which is attached one or more hydroxyl (OH) groups
- plant pigments (anthocyanins, flavonoids_, plant poisons and a number of important med drugs