pKa values to know Flashcards

1
Q

What is the pKa value of HI?

A

-10

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2
Q

What is the pKa value of HBr?

A

-8

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3
Q

What is the pKa value of HCl?

A

-7

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4
Q

What is the pKa value of HF?

A

3

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5
Q

What is the pKa value of an oxocarbenium ion (protonated carbonyl)?

A

-6 to -8

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6
Q

What is the pKa value of an oxonium ion (protonated alcohol/ether)?

A

-2

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7
Q

What is the pKa value of a hydronium ion (protonated water or an aqueous solution of any stronger acid)?

A

-2

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8
Q

What is the pKa value of carboxylic acid? Or a pyridinium ion?

A

5

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9
Q

What is the pKa value of phenol? Or an ammonium ion?

A

10

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10
Q

What is the pKa value of a primary or secondary amide?

A

15

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11
Q

What is the pKa value of water?

A

16

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12
Q

What is the pKa value of alcohols?

A

16-18

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13
Q

What is the pKa value of a-aldehyde, a-ketone?

A

20

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14
Q

What is the pKa of a terminal alkyne?

A

25

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15
Q

What is the pKa of an a-ester, a-amide?

A

25

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16
Q

What is the pKa of hydrogen (H2)?

A

36

17
Q

What is the pKa of ammonia, primary amine, or secondary amine?

A

40

18
Q

What is the pKa of allylic/benzylic? (e.g., PhCH3)

A

41

19
Q

What is the pKa value of arene?

A

43

20
Q

What is the pKa of alkene/vinylic?

A

50

21
Q

What is the pKa value of alkane?

A

50+