Physics Review Flashcards
3 physical states of a substance
solid, liquid, gas
Solid
- Atoms/molecules are closely approximated due to lattice.
- Have volume and shape
- Motion is limited, only vibrate in position
Liquid
- Molecules exert weaker force on each other called Van der waal forces
- allows fluid flow, sliding, and the molecules can move throughout the substance.
- Takes shape of container, has volume.
- Have more kinetic energy
Gas
- Molecules are independent of each other
- Molecules are constantly moving
- No definite shape or volume
- Measured by flowmeters or respirometers
Inverse Relationship
The value of one parameter decreases as the value of the other parameter increases
Direct Relationship
Where two variables do the same thing
Saturated Vapor Pressure
Pressure exerted by a vapor when, at any one temp, an equilibrium is reached at which the same number of molecules are vaporizing as are returning to liquid
Boiling Point
The temp at which vapor pressure becomes equal to atmospheric pressure and at which all liquid changes to gas
Vapor pressure and boiling points are ___ related
inversely related
Force
That which changes or tends to change the state of rest or motion of an object
__=mass x acceleration (Newton’s 2nd law)
Pressure
- Force applied over a surface
- Pa = pascal
- kPa is usual unit utilized
Absolute Pressure
gauge pressure + atmospheric pressure
Boyles Law
- At a constant temperature, the volume of a given gas varies inversely with the absolute pressure.
- P1 x V1 = P2 x V2
Charles Law
at a constant pressure the volume of a given gas varies directly with the absolute temperature
-V1/T1 = V2/T2
Gay Lussac’s Law
at a constant volume the absolute pressure of a given mass of gas varies directly with the absolute temperature
- P1/T1 = P2/T2
Dalton’s Law of Partial Pressures
In a mixture of gases, the pressure exerted by each gas is the same as that it would exert if it was alone in the container.
Avogadro’s Hypothesis
equal volumes of gases at the same temperature and pressure contain equal numbers of molecules (a mole)
1 mole = 6.022x10^23
Universal gas constant
Constants: PV, V/T, P/T
PV/T = universal gas constant
universal gas law (ideal gas law)
PV=nRT
Critical Temperature
the temp above which no amount of pressure can liquefy a gas
Critical pressure
the pressure to liquefy a gas at its critical temperature
Solubility
solution is a homogenous mixture of a solute (gas) in a solvent (liquid)
depends on: partial pressure of gas, temperature, gas, liquid
Henry’s law
at a certain temp, the amount of a given gas dissolved in a given liquid is directly proportional to the partial pressure of the gas in equilibrium with the liquid
La Chatelier’s Principle
a change in any of the factors in determining an equilibrium causes the system to adjust or reduce or counteract the effect of the change.
solubility coefficient
the volume of gas which dissolves in one unit volume of the liquid at the temp concerned
partition coefficient
the ratio of the amount of substance preset in one phase compared with another (the two phases being of equal volume and in equilibrium)
Blood gas partition coefficient
reflects the proportion of the anesthetic that will be absorbed in the blood verses the amount of anesthetic that will leave the blood to diffuse into tissues
oil gas partition coefficient
ratio of a gas present in oil verses in the gas state.
Indicates how efficiently a gas can access and affect the sites of action.
diffusion
the continual movement of molecules among each other in liquids or in gases. Occurs from areas of high concentration to areas of low concentration.