Physical Sciences Flashcards

1
Q

The four kinematic equations are:

A

∆d = Vot + 1/2at2

∆d = (Vavg)t

Vf2 = Vo2 + 2a∆x

Vf = Vo + at

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2
Q

Centripetal force:

A

Fc = (mv2)/r

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3
Q

Centripetal acceleration:

A

ac = v2/r

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4
Q

Power:

A

P = Work/time

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5
Q

Spring mechanics:

A

Fspring = kx

(Force of compression or stretch = spring constant X displacement of spring from equilibrium position)

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6
Q

Elastic potential energy:

A

PEspring = 1/2kx2

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7
Q

Simple harmonic motion (mass on a spring):

A

T = 2π√(m/k)

Period = 2π√(mass/spring constant)

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8
Q

Simple harmonic motion (pendulum):

A

T = 2π√(L/g)

Period = 2π√(pendulum length/acceleration of gravity)

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9
Q

Angular velocity:

A
ω = 2πf (angular velocity = 2π X frequency)
ω = v/r (angular velocity = tangential velocity/radius)
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10
Q

Young’s Modulus:

A

stress/strain

(F/A)/(∆L/L)

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11
Q

Period of circular motion:

A

T = 2π/ω

(Period = 2π/angular velocity)

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12
Q

Ramp force:

A

F = mg(h/d)

(Force = mg(height of ramp/distance along its hypotenuse)

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13
Q

Lever force:

A

F = mg(Lm/Lf)

(Lm and Lf refer to lever arms for mass and applied force)

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14
Q

Hydraulic lift force:

A

F = mg(dl/ds) or F = mg(As/Al)

(dl and ds refer to distances traveled by large and small plunger; Asand Al refer to cross-sectional areas of small and large plunger)

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15
Q

Orbital velocity:

A

v = √(GM/r)

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16
Q

Angular momentum:

A

L = Iω

(angular momentum = moment of inertia X angular velocity)

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17
Q

Second quantum number:

A

l – designates sub-shell; value can be positive integer from 0-(n-1); 0 = s orbital, 1 = *p *orbital, 2 = *d *orbital, 3 = *f *orbital

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18
Q

Third quantum number:

A

m – values range from -l to l; designates orientation of corresponding orbital

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19
Q

Fourth quantum number:

A

s – spin; two values, +1/2 and -1/2

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20
Q

Work function (chemistry):

A

The amount of energy required to eject valence electrons from the surface of a solid metal

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21
Q

Alpha decay:

A

loss of one He nucleus (mass number 4, atomic number 2)

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22
Q

Beta decay:

A

A neutron is changed into a proton with the ejection of an electron

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23
Q

Electron capture:

A

A proton is changed into a neutron via capture of an electron

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24
Q

Positron emission:

A

A proton is changed into a neutron via expulsion of a positron

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25
Gamma emission:
Gamma rays emitted as a byproduct of other types of decay
26
Neutron =
proton + electron
27
Proton =
neutron + positron
28
Condosity of a solution:
the concentration of NaCl that will conduct electricity exactly as well as the solution in question
29
Nitrite:
NO2-
30
Chlorate:
ClO3-
31
Perchlorate:
ClO4-
32
Chlorite:
ClO2-
33
Hypochlorite:
ClO-
34
Carbonate:
CO32-
35
Bicarbonate:
HCO3-
36
Sulfate:
SO42-
37
Phosphate:
PO43-
38
Manganate:
MnO42-
39
Permanganate:
MnO4-
40
Nitrate:
NO3-
41
Specific heat of a substance:
the amount of heat per unit mass required to raise the temperature by one degree Celsius Q = mc∆t (heat added = mass X specific heat X change in temp)
42
Pressure-volume work:
∆Wsystem = -Pext∆V
43
pKa:
measurement of the relative ability of a molecule to give up a proton; a low pKa value indicates that the compound is acidic and will easily give up its proton to a base
44
Specific gravity:
SG = Dsubstance/Dwater
45
Density of water:
1000kg/m3 or 1.0g/cm3
46
For objects floating in liquids, the fraction of the object submerged =
Dobject/Dliquid
47
Buoyant force:
Fbuoyant = pvg = weight of the amount of fluid displaced by object
48
Apparent weight:
AW = aW (actual weight) - Fbuoyant
49
Units of pressure:
1 x 105 Pascals = 1 atm = 760 mmHg = 760 Torr
50
Fluid pressure formula:
Pfluid = density x g x h
51
Flow rate:
Q = A (total cross-section area) X V (flow velocity)
52
Bernoulli's equation:
Pressure + *p*gh + 1/2*p*v2 = constant value (conservation of energy for flowing fluids)
53
Charge of an electron:
e- = 1.6 x 10-19 C | (charge is _quantized_)
54
Constant electric field voltage =
Ed (strength of electric field X distance)
55
Point charge electric field voltage =
Kq/r (K constant X charge/distance)
56
Formula for magnetic force exerted on a charged particle moving in a magnetic field:
F = qvBsinØ [Force = charge X velocity of particle X magnetic field (in Tesla) X angle between v & B]
57
Current =
∆q/∆t
58
Formula for resistance:
R = pL/A (Resistance = resistivity X length/cross-sectional area)
59
Formula for capacitance:
C = Q/V | (capacitance = charge on plate/voltage)
60
Potential energy stored by a capacitor:
U = 1/2CV2
61
Total resistance of resistors in series:
R = R1 + R2 + R3...
62
Total resistance of resistors in parallel:
1/R = 1/R1 + 1/R2 + 1/R3...
63
Total capacitance of capacitors in parallel:
C = C1 + C2 + C3...
64
Total capacitance of capacitors in series:
1/C = 1/C1 + 1/C2 + 1/C3...
65
Total voltage of batteries in series:
add individual voltages directly
66
Total voltage of batteries in parallel:
the highest voltage of any one of the batteries in parallel
67
Formula for electrical power:
P = IV
68
RMS voltage/current/etc:
'root mean square' - take readings from several time intervals, square those values, find the average of those squares, determine square root of that average
69
Intensity:
power/unit area | (Watts/4πr2)
70
Decibel system:
10-fold increases in intensity are represented by 10 unit increases on Richter scale (e.g., sound 100 times more intense = 20 points higher on Richter scale)
71
Speed of light:
3 x 108 m/s
72
Speed of sound:
340 m/s
73
Doppler effect formulas:
∆f/fs = v/c or ∆wavelength/wavelengths = v/c (v = relative velocity, c = speed of wave)
74
Wave rules for non-dispersive medium:
1. frequency never changes when a wave moves from medium to medium 2. wavelength does change when a wave moves from medium to medium
75
Harmonics (matching ends):
wavelength = 2L/n
76
Harmonics (one node, one antinode):
wavelength = 4L/n (gives only the odd harmonics - 1, 3, 5...)
77
The frequency of the first harmonic is called the \_\_.
fundamental frequency | (f = v/2L)
78
The 2nd harmonic can also be called the \_\_.
first overtone (and 3rd harmonic is 2nd overtone, etc.)
79
The frequency of any harmonic is equal to:
n(fundamental frequency)
80
Energy of a photon:
E = hf | (h = Planck's constant)
81
Young's double-slit experiment:
x = (wavelength)L/d (x = distance between fringes, L = distance between slits and screen, d = distance between slits)
82
Electromagnetic radiation - decreasing frequency:
gamma rays \> x-rays \> UV \> visible light \> infrared \> microwaves \> radio waves \> long waves
83
Visible light wavelength range:
390 - 700 nm
84
Index of refraction:
n = c/v (c = speed of light in vacuum, v = speed of light in that medium)
85
Mirror magnification equation:
M = -di/do = hi/ho (d = distance, h = height, i = image, o = object)
86
Thin lens / mirror equation:
1/f = 1/di + 1/do
87
Focal point - convex/concave mirrors:
f = 1/2r
88
Lens/mirror rules:
1. do is always positive 2. di and f are positive if on same side as observer, negative if on opposite side 3. RIP / VUN - real, inverted, positive / virtual, upright, negative (each trio always stay together)
89
Optical power:
inverse of focal point (P = 1/f)
90
Two lens systems:
M = m1m2 P = p1 + p2
91
Amphoteric:
can act as an acid or base (e.g., H2O)
92
Arrhenius acid/base definitions:
acids produce H+ ions in solution, bases produce OH- ions in solution
93
Bronsted-Lowry acid/base definitions:
acids donate protons, bases acept protons
94
Lewis acid/base definitions:
acids accept a pair of electrons, bases donate a pair of electrons
95
Strong acids:
HI, HBr, HCl, HNO3, HClO4, HClO3, H2SO4, H3O+
96
Strong bases:
Group IA hydroxides (NaOH, KOH, etc.), NH2-, H-, Ca(OH)2, Sr(OH)2, Ba(OH)2, Na2O, CaO
97
What is the salt of a weak acid or base?
the conjugate base/acid of that weak acid/base combined with an ion to form a salt
98
When the salts of weak acids or bases dissolve in water,
one of the ions will undergo hydrolysis to re-form the weak acid or base
99
Titration: 1 equivalent =
the amount of acid or base necessary to produce or consume one mole of [H+] ions
100
Titration: at the equivalence/stoichiometric point (midpoint of nearly vertical section):
[titrant] = [analyte]
101
Titration: at the half-equivalence point (midpoint of nearly horizontal section):
[HA] = [A-] (only true for weak conjugate acid/base pairs)
102
Electrical potential =
Eo - reduction potential (larger number = higher potential for reduction)
103
Hydrogen half cell:
2H+ + 2e- = H2, Eo = 0.00V
104
Cell potential:
Eocell or Cell EMF - the sum of the electrical potentials for the two half-reactions that make up an electrochemical cell
105
Cathode:
positive terminal
106
Anode:
negative terminal
107
Cell potential for a Galvanic cell is always \_\_.
positive
108
Cell potential for an electrolytic cell will always be \_\_.
negative
109
Electrolytic cell:
external voltage applied to galvanic cell, forcing the reverse results
110
Nernst equation:
E = Eo - (0.06/n)log[lower]/[higher]
111
Concentration cell:
same electrodes and solution used, reaction driven difference in molarities of two solutions
112
Relationship between free energy and chemical energy:
∆Go = -nFEo (n = moles of electrons transferred, F = Faraday's constant)
113
Faraday's constant:
the charge on one mole of electrons
114
R gas constant:
R = 0.08 L•atm/mol•K = 8.31 J/mol•K
115
Ideal gas assumptions:
gas molecules have no volume and no intermolecular forces
116
Ideal Gas Standard Temperature and Pressure:
P = 1 atm V = 22.4 L n = 1 mole R = 0.08 Latm/molK or 8.31 J/molK T = 273 K
117
Combined Gas Law:
P1V1/T1 = P2V2/T2 (Because PV/T = nR and R is constant, for the same number of moles of gas the ratio of PV/T remains constant)
118
Real gas deviations from Ideal Gas Law:
at extremely high pressure, gas molecules will occupy a greater volume; at extremely low temperature, gas molecules produce a smaller pressure
119
Graham's Law (effusion and diffusion, i.e., gas mixing):
Rate1/Rate2 = √MW2/√MW1 | (MW = molecular weight)
120
Liquids boil when the vapor pressure of the liquid equals \_\_.
atmospheric pressure
121
∆Hfusion =
the amount of energy in J/mol required or removed to go from solid to liquid or liquid to solid, respectively
122
∆Hvaporization =
the amount of energy in J/mol required or removed to go from liquid to gas or gas to liquid, respectively
123
Sublimation:
solid → gas
124
Deposition =
gas → solid
125
Triple point (chemistry):
precise temperature and pressure at which all 3 phases of a substance exist simultaneously in equilibrium with each other
126
Critical point (chemistry):
the precise temp and pressure above which gas and liquid phases become indistinguishable
127
Supercritical fluid (chemistry):
cannot be compressed back into a liquid by increasing pressure, nor can it be turned to gas by increasing temp
128
If energy is added at a constant rate, the phase change from solid to liquid is __ than that from liquid to gas.
shorter
129
The solubility of a gas in a liquid is __ proportional to the partial pressure of the gas over that liquid.
directly
130
Vapor pressure w/ a non-volatile solute:
Vp = XVpo | (x = mole fraction of pure solvent)
131
Total vapor pressue w/ a volatile solute:
XVposolvent + XVposolute
132
Gas solubility: polar and non-polar gases together:
easily form homogenous mixtures
133
Boiling point elevation:
∆T = kbmi (m = molality, i = number of ions formed per molecule)
134
Freezing point depression:
∆T = kfmi (m = molality, i = number of ions formed per molecule)
135
More solute = __ osmotic pressure
higher
136
Osmotic pressure formula:
π = TRiM (i = # ions formed per molecule, M = molarity)
137
Molality:
moles solute / kg solvent
138
Parts per million:
mass solute/total mass solution x 106
139
Colloid:
solvents containing undissolved solute particles too small to be separated by filtration (ex: paint)
140
For unsaturated solutions, the Ksp is __ than the ion product.
greater
141
A __ ion added to a solution might cause precipitation; a __ ion added definitely will not cause precipitation.
common, spectator
142
Prefix: tera-
T - 1012
143
Prefix: giga-
G - 109
144
Prefix: mega-
M - 106
145
Prefix: kilo-
k - 103
146
Prefix: hecto-
h - 102
147
Prefix: micro-
µ - 10-6
148
Prefix: nano-
n - 10-9
149
Prefix: pico-
p - 10-12