Physical Chemisty Flashcards
Standard conditions of temperature and pressure
298K
100KPa
Bond enthalpy
Amount of energy needed to break one mole of the stated bond
Average bond enthalpy
Energy needed to break one mole of bonds in the gas phase averaged over many different compounds
Hess’ law
Regardless of the multiple stages of a reaction, the total enthalpy change for the reaction is the sum of all the changes
Catalyst
Lower activation energy by providing alternative pathways for the bonds to be broken and remade. The catalyst is left unchanged
Heterogeneous catalysts
In a different physical state to reactants
Reaction happens on surface of the catalyst and increasing area means more can react
Homogenous catalyst
Same physical state as the reactants
Usually is a aqueous catalyst, works by making an intermediate species which then reacts to from products and reform the catalyst
Catalyst used to make ethanol
Phosphoric Acid
Le chataliers prunciple
If you change the concentration, pressure or temperature of a reversible reaction, you tend to alter the position of equilibrium
General reaction of equilibrium constant
(D)d(E)e/(A)a(B)b