Physical Chemisty Flashcards

1
Q

Standard conditions of temperature and pressure

A

298K

100KPa

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2
Q

Bond enthalpy

A

Amount of energy needed to break one mole of the stated bond

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3
Q

Average bond enthalpy

A

Energy needed to break one mole of bonds in the gas phase averaged over many different compounds

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4
Q

Hess’ law

A

Regardless of the multiple stages of a reaction, the total enthalpy change for the reaction is the sum of all the changes

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5
Q

Catalyst

A

Lower activation energy by providing alternative pathways for the bonds to be broken and remade. The catalyst is left unchanged

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6
Q

Heterogeneous catalysts

A

In a different physical state to reactants

Reaction happens on surface of the catalyst and increasing area means more can react

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7
Q

Homogenous catalyst

A

Same physical state as the reactants
Usually is a aqueous catalyst, works by making an intermediate species which then reacts to from products and reform the catalyst

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8
Q

Catalyst used to make ethanol

A

Phosphoric Acid

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9
Q

Le chataliers prunciple

A

If you change the concentration, pressure or temperature of a reversible reaction, you tend to alter the position of equilibrium

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10
Q

General reaction of equilibrium constant

A

(D)d(E)e/(A)a(B)b

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