Phase Diagrams Flashcards
What is a phase diagram
A phase diagram is a map which shows the relationship between phases in equilibrium in a system at various temperatures, pressures, and compositions.
What is a phase
A phase is a physically-distinct, chemically-homogeneous and
mechanically-separable region of a system.
What is a component
The components of a system refer to the chemical species that comprise the system. They may be elements, ions or compounds.
explain the phase rule
The phase rule determines the number of independent variables (i.e. degrees of freedom (F)) needed to describe the system at any given point.
It is also known as Gibb’s Equation:
F=C(number of components)-P(number of phases)+2
what happens at the triple point
There are no degrees of freedom. Therefore, in this situation, neither temperature or pressure may be varied without altering one or two of the phases
What is the liquidus
The phase boundary between the liquid and the two phase region is called the liquidus.
What is the solidus
The boundary between the solid and the two phase region is called the solidus.
Describe a euctectic phase diagram
When the solid solubility is limited and the melting points of the components are not vastly different
describe the solvus
When the solid solubility is limited, it is indicated by the phase boundary called the solvus.