PH MEASUREMENT AND BUFFER PREPARATION Flashcards

1
Q

measure of how acidic/basic a solution is.

A

pH

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2
Q

0 to 14.

A

range

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3
Q

pH < 7

A

acidic

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4
Q

pH = 7

A

neutral

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5
Q

pH > 7

A

basic

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6
Q

potential of hydrogen

A

ph

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7
Q

measure of the hydrogen ion (H+) concentration in an aqueous solution

A

pH

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8
Q

expressed as the negative logarithm of the hydrogen-ion concentration.
pH = - log [H+]

A

pH

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9
Q

potential of Hydroxide

A

pOH

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10
Q

measure of hydroxide ion (OH-) concentration

A

pOH

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11
Q

expressed as the negative logarithm of the hydroxide-ion concentration.
pOH = - log [OH-]

A

pOH

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12
Q

important in organism and their cells because chemical reactions and processes are affected by the hydrogen ion concentration.

A

control of pH

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13
Q

requires a pH between 7.8 and 8.4

A

Nemo (Clownfish)

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14
Q

compound that can donate a hydrogen ion.

A

acid

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15
Q

substance that accepts hydrogen ions.

A

base

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16
Q

Hydrogen ions
low ph/ many hydrogen ions

A

ACIDS

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17
Q

(hydroxide ions)
high ph/ many hydroxide ions

A

ALKALIS

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18
Q

Chemists have tried to define acids and bases in relation to their compositions and molecular structures.

A

Background

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19
Q

defines acids as substances that produce H+ ions in aqueous solution while bases are substances that produce OH- ions in aqueous solution.
Pronounced as “svaan-tay”

A

Svante Arrhenius

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20
Q

Mentioned that acids are electron-pair acceptors and bases are electron-pair donor.
However, the two mentioned definitions have limitations. Thus, the most useful and accepted definition of acids and bases nowadays are those proposed by Johannes Bronsted and Thomas Lowry, and it is known as the Bronsted-Lowry theory.

A

Gilbert N. (G.N.) Lewis

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21
Q
  • HCI (Hyrochloric acid) is an acid because it donates a proton making Cl- (Chloride) while water is a base because it accepts a proton making H30+.
  • Furthermore, the theory explains that for every acid-base reaction, there is a creation of conjugate acid-base pair.
  • In the above example Cl- is the conjugated base of HCl and H30+ is the conjugated acid of water as shown below.
A

Rationale:

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22
Q

introduced the pH scale that measures the strength of an aqueous acidic or basic solution.
It converts the H+ concentrations to pH using the formula.
pH = - log [H+]

A

Seren Peter Lauritz Sorensen
(S.P.L.) Sorensen

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23
Q

is “the negative common logarithm of the activity of hydrogen ion in solution

A

precise definition of pH

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24
Q

The pH of a solution is the negative logarithm of the hydrogen-ion concentration.
pH = -log|H+]

A

Computation of pH & [H+]

25
compute for the pH of pure water with [H+] = 1.0 × 10 -7 M (Molarity).
pH = -log|H + ] = - 10g|1.0 × 10 -7] = -(-7.00) pH = 7.00
26
compute for the pH of pure water with [H+] = 1.0 × 10 -7 M (Molarity).
pH = -log|H + ] = - 10g|1.0 × 10 -7] = -(-7.00) pH = 7.00
27
Compute for the pH of solution with [H+] = 2.3 × 10-5 M
pH = -log[H + ] = - 10g|2.3 × 10 -5] pH = 4.64 (Acidic)
28
compute for the [H+] if pH is known using this formula:
[H+] = 10^-рН *Use the 10^x key on your calculator
29
What is the [H+] of a solution with a pH of 9.14?
[Н+] = 10^-рН = 10^-9.14 [H+] = 7.24 × 101-10 M
30
What is the [H+] of a solution with a pH of 5.4?
[H+] = 10^-pH =101-5.4 [H+] = 3.98 × 101-6 M
31
The pOH of a solution is the negative logarithm of the hydroxide-ion concentration. рОН = -log[OH-] [ОН-] = 10^-рОН *Use the 10^x key on your calculator Constant: pH + pOH = 14
Computation of poH
32
The pOH of a solution is the negative logarithm of the hydroxide-ion concentration. рОН = -log[OH-] [ОН-] = 10^-рОН *Use the 10^x key on your calculator Constant: pH + pOH = 14
Computation of poH
33
A solution has a pH of 4. Find the pOH and [OH-].
pH + pOH = 14 рОН = 14 - рН рОН = 14 - 4 рОН = 10 [ОН-] = 10^-рОН = 10^-10 [OH-] =1 × 10^-10 M
34
Find the pOH and [OH-] of a solution with a pH of 8.4.
pH + pOH = 14 рОН = 14 - рн рОН = 14 - 8.4 рОн = 5.6 [ОН-] = 10^-рОН = 10^-5.6 [OH-] = 2.5 × 10^-6 M
35
If pH > 7 = Basic , <7 = Acidic If pOH >7 = Acidic , <7 = Basic 7 = Neutral
Interpretation of Results
36
prevent changes in pH.
Buffers
37
resist changes in the pH even when acids or bases are added.
Buffers
38
are a mixture of a weak acid or alkali and one of its salts. Ex: acetic acid + sodium acetate
Buffers
39
The ability of buffers to resist large changes in pH is governed by
Le Chatellier's principle.
40
A principle of equilibrium shift due to changes in buffer conditions.
La Chatellier's Principle
41
In our blood, carbonic acid is the most important buffer. This solution maintains our blood pH to facilitate transport of oxygen from the lungs to the cells.
Buffers in Human Blood
42
normally slightly basic (7.35 to 7.45)
pH of blood
43
simple test to check if a substance is acidic or basic using a litmus paper.
Litmus Test
44
types of litmus paper available that can be used to identify acids and bases
red litmus paper and blue litmus paper
45
turns red for acidic pH
Blue litmus paper
46
turns blue for basic pH
Red litmus paper
47
No color change
neutral pH
48
impregnated with organic compounds that change their color at different pH values. The color shown by the paper is then compared with a color standard usually provided by the manufacturer.
Indicator Paper
49
impregnated with organic compounds that change their color at different pH values. The color shown by the paper is then compared with a color standard usually provided by the manufacturer.
Indicator Paper
50
should be calibrated first before being operating the device. The standard procedure for calibrating a pH meter is to calibrate it at three different pHs (pH 7, pH 4, and pH 10). After calibration, all that needs to be done is to insert the electrodes of the pH meter into the solution to be tested and read the pH flashed on the screen.
pH Meter
51
an indicator that can be used to determine the pH value of a solution
pH PAPER
52
an indicator that is used to determine the acidity or the basicity of a solution
LITMUS PAPER
53
Can give the exact pH value of a solution
pH PAPER
54
Cannot give the exact pH value of a solution
LITMUS PAPER
55
Give more precise results
pH PAPER
56
Give a less precise indication
LITMUS PAPER
57
Can give a range of colors
pH PAPER
58
Can give only two colors
LITMUS PAPER